Chalcogen-bonding-mediated chiral recognition and enantioenrichment of organoselenocyanates. [PDF]
Wang T, Hao A, Xing P.
europepmc +1 more source
Halogen‐Mediated Polymer‐Free Recovery of Pristine MoS2 Monolayers From Gold‐Assisted Exfoliation
Schematic procedure for halogen‐mediated polymer‐free recovery of pristine MoS2 monolayers from gold‐assisted exfoliation. ABSTRACT Metal‐assisted mechanical exfoliation has recently emerged as a powerful strategy for producing large‐area monolayers of two‐dimensional (2D) transition‐metal dichalcogenides (TMDs) with near‐intrinsic crystalline quality.
Jeyavelan Muthu +4 more
wiley +1 more source
A Crystalline and Thermally Stable Selenocysteine Selenenic Acid
The long‐sought catalytic intermediate of selenoproteins, selenocysteine selenenic acid (Sec–SeOH), is isolated for the first time at ambient temperature. A bioinspired selenopeptide sequence encapsulated within a protective molecular cradle and an oxidant‐free route from selenenyl iodide (Sec–SeI) enable the isolation of Sec–SeOH. Contrary to the long‐
Ryosuke Masuda, Satoru Kuwano, Kei Goto
wiley +2 more sources
Hierarchical on-surface assembly of nanoribbons through concurrent hydrogen- and chalcogen-bonding interactions. [PDF]
Caporale A +7 more
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Alkali Chalcogenido Dialuminates A 6[Al2 Q 6] (A = K, Rb, Cs; Q = S, Se, Te)
Seven new alkali chalcogenido aluminates A6[Al2Q6] (A = K‐Cs, Q = S‐Te) complement the family of simple metallates(III) A6[M2Q6] (M = Al‐In, FeIII) with dinuclear anions of two edge sharing [AlQ4] tetrahedra. Despite the similar anions, straightforward bonding situation and physical properties, these metallates crystallize in seven different structure ...
Michael Schwarz +2 more
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Redox-Controlled Chalcogen Bonding as a Modulator of ZnCl<sub>2</sub> Chelation and Transport. [PDF]
Jiang Y, Gabbaï FP.
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The isolation and solid‐state structures of the two disulfate‐containing pnictogenates [SeCl3][Pn(S2O7)2] (Pn = Sb, Bi), as well as the mixed‐anionic As2[S2O7]2[S3O10] are presented. The former two consist of complex ∞1{[Pn(S2O7)1/1t(S2O7)2/2e]‐}$$ {\infty }^{1}\left\{{\left[\mathrm{Pn}{\left({\mathrm{S}}_{2}{\mathrm{O}}_{7}\right)}_{1/1}^{\mathrm{t}}{\
Jan Langwald +5 more
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Chalcogen bonding-directed photoresponsive helix from azo-fused H-bonded arylamide foldamers. [PDF]
Liu CZ +9 more
europepmc +1 more source
S‐Adenosylmethionine (SAM) hydrolases counter increased SAM epimerisation in thermophilic archaea
S‐Adenosyl‐l‐methionine (SAM) is a vital enzyme cofactor. Epimerisation at the sulfonium centre of biologically active (SS,SCα)‐SAM is driven by heat, yielding biologically inactive (RS,SCα)‐SAM. Here, two novel archaeal SAM hydrolases from the thermophilic Sulfolobus acidocaldarius and the halophilic Haloferax volcanii are shown to cleave (RS,SCα)‐SAM.
Agnes Bartels +7 more
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Interplay between Inter- and Intramolecular Halogen-/Chalcogen-Bonding in Two-Molecule Aggregates Featuring Te<sup>II</sup>···I Secondary-Bonding Interactions and in Their Congeners. [PDF]
Gomila RM, Frontera A, Tiekink ERT.
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