Evidence for and evaluation of fluorine-tellurium chalcogen bonding. [PDF]
Chem Sci, 2023 The first in-depth characterization of Te–F chalcogen bonding in solution was achieved by designing and preparing specific Te derivatives followed by their NMR study.
Weiss R +4 more
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Selenium(IV) Polybromide Complexes: Structural Diversity Driven by Halogen and Chalcogen Bonding [PDF]
Molecules, 2022 Reactions between bromoselenate(IV)-containing solutions, dibromine and salts of pyridinium-family organic cations resulted in structurally diverse, bromine-rich polybromine-bromoselenates(IV): (4-MePyH)5[Se2Br9][SeBr6](Br3)2 (1), (2-MePyH)2{[SeBr6](Br2)}
Nikita A. Korobeynikov +5 more
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Polymorphism, Halogen Bonding, and Chalcogen Bonding in the Diiodine Adducts of 1,3- and 1,4-Dithiane [PDF]
Molecules, 2021 Through variations in reaction solvent and stoichiometry, a series of S-diiodine adducts of 1,3- and 1,4-dithiane were isolated by direct reaction of the dithianes with molecular diiodine in solution.
Andrew J. Peloquin +4 more
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Chalcogen bonding in coordination chemistry
Coordination Chemistry Reviews, 2022 The chalcogen bond (ChB) is defined as a noncovalent interaction between the electron density deficient region (so-called as sigma or pi hole) of a covalently bonded chalcogen atom and a nucleophilic (Nu) site in the same (intramolecular) or another (intermolecular) molecular entity: R-Ch center dot center dot center dot Nu [Ch = O, S, Se or Te; R = C,
A J L Pombeiro +2 more
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Chalcogen Bonding in Co-Crystals: Activation through 1,4-Perfluorophenylene vs. 4,4′-Perfluorobiphenylene Cores [PDF]
Molecules, 2021 The ability of alkylseleno/alkyltelluroacetylenes such as bis(selenomethylethynyl)-perfluorobenzene (4F-Se) to act as a ditopic chalcogen bond (ChB) donor in co-crystals with ditopic Lewis bases such as 4,4′-bipyridine is extended here to the ...
Arun Dhaka +4 more
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Carbon–Halogen Bond Activation by Selenium‐Based Chalcogen Bonding [PDF]
Angewandte Chemie - International Edition, 2017 AbstractChalcogen bonding is a little explored noncovalent interaction similar to halogen bonding. This manuscript describes the first application of selenium‐based chalcogen bond donors as Lewis acids in organic synthesis. To this end, the solvolysis of benzhydryl bromide served as a halide abstraction benchmark reaction.
Daniel B Werz, Stefan M Huber
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Chalcogen Bonding due to the Exo-Substitution of Icosahedral Dicarbaborane [PDF]
Molecules, 2019 Chalcogen atoms are a class of substituents capable of generating inner and outer derivatives of boron clusters. It is well known that chalcogenated boron clusters can form strong σ-hole interactions when a chalcogen atom is a part of an icosahedron.
Jindřich Fanfrlík +2 more
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Selective recognition and extraction of iodide from pure water by a tripodal selenoimidazol(ium)-based chalcogen bonding receptor [PDF]
iScienceSummary: A selenium-based tripodal chalcogen bond (ChB) donor TPI-3Se is demonstrated for the recognition and extraction of I− from 100% water medium. NMR and ITC studies with the halides reveal that the ChB donor selectively binds with the large, weakly
Abu S.M. Islam +4 more
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Thermodynamics of Anion Binding by Chalcogen Bonding Receptors [PDF]
Chemistry - A European Journal, 2018 AbstractThe application of chalcogen bonding (ChB) to anion recognition is an underdeveloped area of host–guest supramolecular chemistry. The chemical instability of heavier chalcogen derivatives may in part be responsible for the lack of progress. Herein, the synthesis of a new structurally simple, tellurium‐based ChB binding motif is reported, the ...
Yuan Chong Jason Lim +2 more
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From Chalcogen Bonding to S–π Interactions in Hybrid Perovskite Photovoltaics [PDF]
Advanced ScienceThe stability of hybrid organic–inorganic halide perovskite semiconductors remains a significant obstacle to their application in photovoltaics. To this end, the use of low‐dimensional (LD) perovskites, which incorporate hydrophobic organic moieties ...
Weifan Luo +29 more
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