Results 51 to 60 of about 3,178 (211)

Clustomesogen Showing Sub‐Zero Liquid Crystal Properties: Supramolecular Assembly Between Cs2[Mo6Ii8(OCOC2F5)6] and Hexaethylenoxide Containing Mesogenic Dimers

open access: yesAdvanced Materials, EarlyView.
Associating a red‐NIR phosphorescent octahedral hexanuclear molybdenum cluster compound with hexaethyleneoxide chains bearing mesogenic units on both ends leads to an emissive hybrid liquid crystal showing mesomorphism on a very unusual temperature range down to −25°C.
Killiann Heinz   +11 more
wiley   +1 more source

Bond orders for intermolecular interactions in crystals: charge transfer, ionicity and the effect on intramolecular bonds

open access: yesIUCrJ, 2018
The question of whether intermolecular interactions in crystals originate from localized atom...atom interactions or as a result of holistic molecule...molecule close packing is a matter of continuing debate.
Khidhir Alhameedi   +3 more
doaj   +1 more source

Noble Gas Bonding Interactions Involving Xenon Oxides and Fluorides

open access: yesMolecules, 2020
Noble gas (or aerogen) bond (NgB) can be outlined as the attractive interaction between an electron-rich atom or group of atoms and any element of Group-18 acting as an electron acceptor.
Antonio Frontera
doaj   +1 more source

On the Importance of σ–Hole Interactions in Crystal Structures

open access: yesCrystals, 2021
Elements from groups 14–18 and periods 3–6 commonly behave as Lewis acids, which are involved in directional noncovalent interactions (NCI) with electron-rich species (lone pair donors), π systems (aromatic rings, triple and double bonds) as well as ...
Antonio Frontera, Antonio Bauzá
doaj   +1 more source

MOCVD‐Grown MoS2 Wafers as a Transfer‐Free Platform for Top‐Gate Devices via Dry Interface Engineering

open access: yesAdvanced Materials, EarlyView.
We reveal the electronic origin of hidden interfacial doping in monolayer MoS2 grown by MOCVD, identifying sulfate related and water like species as intrinsic donors. Through dry interface engineering approach, we demonstrate MOCVD‐grown single‐crystal MoS2 wafers as a transfer‐free platform for the reliable evaluation of intrinsic gate stacks and ...
Shuhong Li   +12 more
wiley   +1 more source

The Copper(II)-Thiodiacetate (tda) Chelate as Efficient Receptor of N9-(2-Hydroxyethyl)Adenine (9heade): Synthesis, Molecular and Crystal Structures, Physical Properties and DFT Calculations of [Cu(tda)(9heade)(H2O)]·2H2O

open access: yesMolecules, 2023
Considering that Cu(tda) chelate (tda: dithioacetate) is a receptor for adenine and related 6-aminopurines, this study reports on the synthesis, molecular and crystal structures, thermal stability, spectral properties and DFT calculations related to [Cu ...
Carmen Rosales-Martínez   +5 more
doaj   +1 more source

Photo‐ and Thermally‐Induced Huge Layer Decoupling in Twisted Bilayer WSe2

open access: yesAdvanced Materials, EarlyView.
A newly developed automated dark‐field tomography visualizes twist‐angle‐dependent structural relaxation and quantifies 3D structures in twisted bilayer WSe2. This approach reveals the evolution of local stacking configurations, thermally induced sub‐ångström interlayer decoupling, and light‐driven interlayer expansion on picosecond timescales ...
A. Nakamura   +10 more
wiley   +1 more source

Thermodynamic Study of Tl6SBr4 Compound and Some Regularities in Thermodynamic Properties of Thallium Chalcohalides

open access: yesAdvances in Materials Science and Engineering, 2017
The solid-phase diagram of the Tl-TlBr-S system was clarified and the fundamental thermodynamic properties of Tl6SBr4 compound were studied on the basis of electromotive force (EMF) measurements of concentration cells relative to a thallium electrode ...
Dunya Mahammad Babanly   +4 more
doaj   +1 more source

Far‐Infrared Hyperbolic Phonon–Polaritons in Zirconium Disulfide

open access: yesAdvanced Materials, EarlyView.
An unpatterned ZrS2${\rm ZrS}_2$ flake, coupled to far‐field infrared light by metal nanoribbons, reveals hyperbolic phonon polaritons with multiple higher‐order branches and effective refractive indices up to 223. This resonator‐assisted approach establishes ZrS2${\rm ZrS}_2$ as a compact van der Waals platform for deeply subwavelength far‐infrared ...
Subhodip Saha   +7 more
wiley   +1 more source

Facile Access to 2-Selenoxo-1,2,3,4-tetrahydro-4-quinazolinone Scaffolds and Corresponding Diselenides via Cyclization between Methyl Anthranilate and Isoselenocyanates: Synthesis and Structural Features

open access: yesMolecules, 2022
A practical method for the synthesis of 2-selenoxo-1,2,3,4-tetrahydro-4-quinazolinone was reported. The latter compounds were found to undergo facile oxidation with H2O2 into corresponding diselenides.
Vladimir K. Osmanov   +13 more
doaj   +1 more source

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