Results 141 to 150 of about 3,871 (214)

Alkali Chalcogenido Dialuminates A 6[Al2 Q 6] (A = K, Rb, Cs; Q = S, Se, Te)

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Seven new alkali chalcogenido aluminates A6[Al2Q6] (A = K‐Cs, Q = S‐Te) complement the family of simple metallates(III) A6[M2Q6] (M = Al‐In, FeIII) with dinuclear anions of two edge sharing [AlQ4] tetrahedra. Despite the similar anions, straightforward bonding situation and physical properties, these metallates crystallize in seven different structure ...
Michael Schwarz   +2 more
wiley   +1 more source

Isolation and Structural Elucidation of the Pnictogen Polysulfate Compounds As2[S2O7]2[S3O10] and [SeCl3][Pn(S2O7)2] (Pn = Sb, Bi)

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The isolation and solid‐state structures of the two disulfate‐containing pnictogenates [SeCl3][Pn(S2O7)2] (Pn = Sb, Bi), as well as the mixed‐anionic As2[S2O7]2[S3O10] are presented. The former two consist of complex ∞1{[Pn(S2O7)1/1t(S2O7)2/2e]‐}$$ {\infty }^{1}\left\{{\left[\mathrm{Pn}{\left({\mathrm{S}}_{2}{\mathrm{O}}_{7}\right)}_{1/1}^{\mathrm{t}}{\
Jan Langwald   +5 more
wiley   +1 more source

S‐Adenosylmethionine (SAM) hydrolases counter increased SAM epimerisation in thermophilic archaea

open access: yesThe FEBS Journal, EarlyView.
S‐Adenosyl‐l‐methionine (SAM) is a vital enzyme cofactor. Epimerisation at the sulfonium centre of biologically active (SS,SCα)‐SAM is driven by heat, yielding biologically inactive (RS,SCα)‐SAM. Here, two novel archaeal SAM hydrolases from the thermophilic Sulfolobus acidocaldarius and the halophilic Haloferax volcanii are shown to cleave (RS,SCα)‐SAM.
Agnes Bartels   +7 more
wiley   +1 more source

Room Temperature Wafer‐Scale Synthesis of Highly Transparent and Conductive p‐Type Sulfur‐Doped Copper Iodide

open access: yesENERGY &ENVIRONMENTAL MATERIALS, Volume 9, Issue 5, September 2026.
Wafer‐scale, room temperature synthesis of S‐doped CuI achieves high‐performance transparent p‐type electrodes. Pre‐doping enables precise control of crystallinity and hole density, yielding 86% transmittance and 75 Ω sq−1 sheet resistance. A record‐high figure of merit of 95 000 MΩ−1 and excellent flexibility across diverse substrates are demonstrated.
Sungsan Kang   +13 more
wiley   +1 more source

Ionothermal Synthesis of Cu(Sb2Se3)[AlCl4] and Cu5(Bi2Se3)6[AlCl4]5 : Monolayers of Sb2Se3 and Bi2Se3 Stabilized by Cu[AlCl4]

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 12, 3 August 2026.
Ionothermal synthesis in Lewis‐acidic ionic liquids (ILs) yields two new low‐dimensional pnictogen–selenide networks cocrystallized with Cu[AlCl4]. Both are narrow‐gap semiconductors that exhibit strong absorption throughout the visible range. Topochemical AlCl3 extraction triggers partial delamination, pointing to a viable route toward 2D derivatives.
Oliver Dreimann   +2 more
wiley   +1 more source

From Behavior to Dynamics: Decoding Carrier Roles in Cu‐based Photocathodes for Solar‐Driven CO2 Reduction

open access: yesAdvanced Materials, Volume 38, Issue 44, 7 August 2026.
The performance of Cu‐based photocathodes in photoelectrochemical CO2 reduction is not governed by catalytic sites alone, but by the dynamic journey of photogenerated carriers. This review decodes how carrier generation, recombination, transport, accumulation, extraction, and electrolyte coupling shape catalytic activity, selectivity, and stability ...
Yi‐Cheng Wang   +5 more
wiley   +1 more source

Charge Transport in All‐Inorganic CuInSe2 Nanocrystal Transistors: Linking Material Design and Device Performance

open access: yesAdvanced Electronic Materials, Volume 12, Issue 15, 10 August 2026.
This work explores how colloidal CuInSe2 nanocrystals form functional field‐effect transistors when their native ligands are replaced with short inorganic species that promote charge transport. By systematically adjusting nanocrystal dimensions, surface treatments, film characteristics, and device architecture, the study maps the resulting electronic ...
Nadia Günther   +8 more
wiley   +1 more source

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