Results 141 to 150 of about 1,488 (236)
Optoelectronics of Single Mixed Dislocations in Van Der Waals Core‐Shell Nanowires
Ge1‐xSnxS van der Waals core‐shell nanowires can host single helical dislocations whose character is tunable from a pure screw to a majority edge dislocation via the core‐shell lattice mismatch. Cathodoluminescence shows profound effects once an edge component is introduced, notably a lowering of the spontaneous emission quantum efficiency due to the ...
Eli Sutter, Peter Sutter
wiley +1 more source
Azidoborylene photolysis results in the isolation of a reactive C═B═N═C heterocumulene bearing an ambiphilic boron centre. Addition of 3O2 to this species results in the clean conversion to a unique example of a dioxaborirane. ABSTRACT Oxidation of the formal boron(0) complex MeCAAC2B in the presence of tetrabutylammonium azide leads to the formation ...
Hayley King +4 more
wiley +2 more sources
Torsion and Axial Deformations of Chalcogen Helical Chains (S, Se, Te): First Principles Calculations Using Line Symmetry Groups. [PDF]
Evarestov RA +3 more
europepmc +1 more source
A distinct semi‐confined inner‐tube chemical vapor deposition geometry enables reproducible, large‐area growth of phase‐pure 2D β′‐In2Se3 from InI + Se precursors. Engineering local vapor transport and optimizing precursor delivery and temperature–time conditions yield uniform continuous films.
Dasun P. W. Guruge +8 more
wiley +1 more source
Steric Pruning Unlocks Hierarchical Structuring, Thermochromism, C-H/O Activation, and 6-electron Redox Transmetalation in Planar Bismuth Triamides. [PDF]
Howlett WP +5 more
europepmc +1 more source
Structure–activity relationships of antioxidant activities of selenides were established by experimental and computational methods. Several structures displayed strong catalytic activity in an NMR‐based assay. Diverse selenides were shown to act as potent catalytic antioxidants.
Adrian I. Doig, Wen Zhou, Thomas G. Back
wiley +1 more source
Theoretical Investigation of Stacked Two-Dimensional Transition-Metal Dichalcogenide Materials: The Role of Chemical Species and Number of Monolayers. [PDF]
Bracht JM +3 more
europepmc +1 more source
The molecular basis of thioredoxin reductase inhibition by antibacterial gold(I) compounds is disclosed. X‐ray crystallography and high‐resolution ESI‐MS reveal selective gold coordination to catalytically relevant cysteine residues of Bc‐TrxR, leading to stable protein–gold adducts and disruption of enzyme redox activity.
Stefano Zineddu +7 more
wiley +1 more source
Alkali chalcogenides-assisted vapor-liquid-solid growth of WX<sub>2</sub> (X = S, Se, Te). [PDF]
Chiang YC +6 more
europepmc +1 more source
This study reveals that square planar Pd and Pt complexes can act as nucleophiles, forming directional triel bonds with boron‐based acceptors. Using energy decomposition analysis (EDA), quantum theory of atoms in molecules (QTAIM), and natural bond orbital (NBO), we demonstrate a transition from dispersion‐driven to dative‐covalent interactions.
Rosa M. Gomila, Antonio Frontera
wiley +1 more source

