Results 171 to 180 of about 472 (205)

National Context and STEM Career Expectations: Social Comparison and Gender Differences Across 72 Economies

open access: yesThe Career Development Quarterly, EarlyView.
ABSTRACT Adolescents’ career expectations play a pivotal role in shaping identity and future opportunities, yet little is known about how national‐level comparisons influence these expectations. Drawing on social comparison theory, this study examines how relative standing in science achievement, socioeconomic status (SES), and math self‐efficacy is ...
Luyang Guo
wiley   +1 more source

Interface‐Engineered Li–Ni–O/Ni Heterostructures With Tunable Vacancies on Biochar Enable Biomass‐to‐Hydrogen Conversion

open access: yesCarbon Energy, EarlyView.
This study shows that lithium induces Li–Ni–O/Ni heterostructures on biochar, creating oxygen vacancies and optimal acid–base environments that enhance steam activation and suppress carbon deposition. These interfacial effects and synergistic modulation lead to high hydrogen yields at moderate temperatures, providing a scalable catalyst design strategy
Jiali Guo   +7 more
wiley   +1 more source

Stereoretentive Nucleophilic Aromatic Substitution Accesses Atropisomeric 4‐Amino‐N‐Arylquinolinium Salts

open access: yesChemistry – A European Journal, EarlyView.
Quinolin‐4‐ones were converted to chloroquinolinium salts, allowing formation of axially chiral aminoquinolinium salts via an enantioretentive SNAr reaction with a variety of amine nucleophiles. The salts have a high rotational barrier, with a racemization half‐life of ∼1000s of years.
Darren Holmes   +5 more
wiley   +1 more source

Hybrid Macrocyclic Peptides — Synthetic Strategies to Diversify and Cyclize Peptide Libraries in Phage Display Selections

open access: yesChemistry – A European Journal, EarlyView.
Hybrid macrocyclic peptides unite genetically encoded peptide libraries with the structural complexity of synthetic small molecules. This Review critically analyzes phage‐compatible cyclization and diversification chemistries, highlights emerging opportunities beyond traditional cysteine‐based approaches, and outlines how future advances may enable the
Titia Rixt Oppewal, Clemens Mayer
wiley   +1 more source

Mechanisms of cancer-induced neurophysiological dysfunction and therapeutic strategies. [PDF]

open access: yesDiscov Oncol
Mujinya R   +6 more
europepmc   +1 more source

Nonparametric maximum likelihood estimation of the survival function using current lifetime data

open access: yesCanadian Journal of Statistics, EarlyView.
Abstract An issue when estimating the failure time survival function is how to set up a prevalent cohort study infrastructure to follow subjects after enrollment. This problem can be circumvented through the well‐known Grenander density estimator using current lifetime observations only.
James H. McVittie, Masoud Asgharian
wiley   +1 more source

Arabidopsis AUGMIN8 Contains Two Independent Microtubule Association Domains

open access: yesCytoskeleton, EarlyView.
ABSTRACT Plant cells create a plasma membrane‐associated network of microtubules that are nucleated by γ‐tubulin ring complexes primarily through microtubule‐dependent microtubule nucleation (MDMN). This dynamic array organizes into specific patterns in response to developmental and environmental cues to influence primary cell wall construction.
Naveen K. Chana   +2 more
wiley   +1 more source

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