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Chemical and Biological Kinetics [PDF]
Russian Chemical Reviews, 1980 Examples of the application of the methods and ideas of chemical kinetics in various branches of chemistry and biology are considered and the results of studies on the kinetics and mechanisms of autoxidation and inhibited and catalysed oxidation of organic substances in the liquid phase are surveyed.
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Chemical Kinetics and Dynamics
Annals of the New York Academy of Sciences, 2003Abstract: Chemical reactions correspond to irreversible processes creating entropy. Chemistry belongs to the class of nonintegrable Poincare systems. In general, chemistry is associated with resonances—transitions of quantum states. We have studied some very simple examples of such processes, like decay of an unstable state, in detail. (In such cases,
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1980
Publisher Summary This chapter discusses atoms, molecules, or ions as they collide, the conditions under which they might react with each other, and the energy changes involved. It explains how the concentration of the reactants, the temperature, the amount of contact among the reacting substances, and catalysis can affect reaction rates.
Therald Moeller +5 more
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Publisher Summary This chapter discusses atoms, molecules, or ions as they collide, the conditions under which they might react with each other, and the energy changes involved. It explains how the concentration of the reactants, the temperature, the amount of contact among the reacting substances, and catalysis can affect reaction rates.
Therald Moeller +5 more
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Chemical Kinetics and Catalysis
1995Utilizing a didactical approach, the authors describe the kinetic theory of catalytic reactions and kinetics is related to the molecular properties of the reacting species. The volume opens with a historical overview of how the fields of catalysis and kinetics developed.
Santen, van, R.A. +1 more
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2015
Chemical reaction types, reaction orders, and the law of mass action that describes the rates of reactions are presented. The Arrhenius rate constant expression and methods for analysis of rate constants, including transition state and recombination rate theories, are discussed as well as the effects of pressure and temperature.
Irvin Glassman +2 more
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Chemical reaction types, reaction orders, and the law of mass action that describes the rates of reactions are presented. The Arrhenius rate constant expression and methods for analysis of rate constants, including transition state and recombination rate theories, are discussed as well as the effects of pressure and temperature.
Irvin Glassman +2 more
+7 more sources
Joint kinetics: a new paradigm for chemical kinetics and chemical engineering
Current Opinion in Chemical Engineering, 2020Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed. Its main idea is performing a battery of kinetic experiments from special initial compositions accompanied by the analysis of the information obtained. Within the developed theory, new basic concepts are presented: events and maps of events; new invariances ...
Gregory S Yablonsky +2 more
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1998
Throughout much of this book we have emphasized the description of a system in terms of an equilibrium state. This approach is invaluable when we are beginning study and are not sure exactly what are the elements and the linkages that comprise the rules of the system under study. Still it seems to be a compulsive pulse taking that is stodgy.
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Throughout much of this book we have emphasized the description of a system in terms of an equilibrium state. This approach is invaluable when we are beginning study and are not sure exactly what are the elements and the linkages that comprise the rules of the system under study. Still it seems to be a compulsive pulse taking that is stodgy.
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1977
Publisher Summary This chapter reviews the fundamental areas of chemical kinetics. Flames will propagate through only those chemical mixtures that are capable of reacting quickly enough to be considered explosive. Indeed, the expression “explosive” essentially specifies very rapid reaction.
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Publisher Summary This chapter reviews the fundamental areas of chemical kinetics. Flames will propagate through only those chemical mixtures that are capable of reacting quickly enough to be considered explosive. Indeed, the expression “explosive” essentially specifies very rapid reaction.
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2009
Chemical kinetics is the aspect of chemistry that deals with the speed or rate of chemical reactions and the mechanisms by which they occur. The rate of a chemical reaction is a measure of how fast the reaction occurs, and it is defined as the change in the amount or concentration of a reactant or product per unit time.
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Chemical kinetics is the aspect of chemistry that deals with the speed or rate of chemical reactions and the mechanisms by which they occur. The rate of a chemical reaction is a measure of how fast the reaction occurs, and it is defined as the change in the amount or concentration of a reactant or product per unit time.
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Chemical equilibrium and chemical kinetics
2018Abstract Building on the previous chapter, this chapter examines gas phase chemical equilibrium, and the equilibrium constant. This chapter takes a rigorous, yet very clear, ‘first principles’ approach, expressing the total Gibbs free energy of a reaction mixture at any time as the sum of the instantaneous Gibbs free energies of each ...
Dennis Sherwood, Paul A. Dalby
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