Cyclometalated Au(III) Complexes With C*N^N, N^C*N, and C*N Ligands Through C–H Activation
The complexes [Au(QPhPy)Cl][AuCl4], [Au(QPhCF3Py)Cl][AuCl4], [Au(QPhtBuPy)Cl][AuCl4], [Au(QPhPy)Cl]Cl, [Au(QPyPh)Cl2], [Au(QPyPhCF3)Cl2], [Au(QPyPhtBu)Cl2], [Au(bpyAn)Cl][AuCl4], and [Au(phenAn)Cl][AuCl4] (Q = 8‐quinolinyl, Ph = phenyl, An = anthracen‐9‐yl, Py = pyridyl, bpy = 2,2′′‐bipyridyl, phen = 1,10‐phenanthrolinyl) containing N*C^N, N*C, and NN ...
Pascal L. Jurzick +5 more
wiley +1 more source
A photocleavable peptidic Ru(ii) mass-tag enabling targeted DESI and MALDI mass spectrometry imaging in cancer tissues. [PDF]
Park M +8 more
europepmc +1 more source
The chelating imino groups in [MCl4(DADDTEthane)] (M = Ti, Zr, Hf) give rise to a planar five‐membered (‐N=C‐C=N‐)M metallacycle. The two thiophene rings of the ligand backbone reside in a noncoplanar arrangement concerning the metallacycle, giving rise to two chiral C–C axes in the ligand backbone.
Dirk Schlüter +3 more
wiley +1 more source
Retracted: Fluorescent Carbon Dot-Supported Imaging-Based Biomedicine: A Comprehensive Review
Bioinorganic Chemistry and Applications
doaj +1 more source
Shape-Directed Hydrothermal Design of Zinc Oxide Nanoparticles for Antimicrobial and Anticancer Applications. [PDF]
Özkan EH +3 more
europepmc +1 more source
More π, less Gap: Band Gap Tuning in Hybrid Antimony Halide Charge Transfer Semiconductors
Extending the π‐conjugation of the organic cation from bipyridinium to phenanthrolinium in hybrid antimony chloride charge transfer semiconductors reduces the band gap from 2.6 to 2.1 eV. This demonstrates that modifying the organic cation's π‐system enables band gap tuning in hybrid charge transfer semiconductors.
Jakob Blahusch +3 more
wiley +1 more source
Synthesis, Structural Characterization, and DFT Studies of Fe(III), Co(II), and Ni(II) Mixed-Ligand Complexes With Albendazole and Nifuroxazide With Molecular Docking Against Respiratory Pathogen Targets. [PDF]
S YA, El-Lateef HMA, Khalaf MM, Abdou A.
europepmc +1 more source
Hydrogen Bond Mediated Dioxygen Activation in a Manganese Guanidine Complex
The guanidine arms of [Mn(DIG3tren)]2+ provide the reducing equivalents and H‐bonding stabilization necessary for the bimolecular activation of O2 to form a mixed valent MnIII(m‐O)2MnIV species. A high‐spin manganese(II) complex supported by a guanidine‐based DIG3tren (tris(N’, N”‐diisopropylguanidinyl‐2‐ethyl)amine) ligand has been synthesized and ...
Matthias Jux, Kallol Ray
wiley +1 more source
Disulfide modification and thiol protection via tris(trimethylsilyl)silane-mediated hydrosilylation of disulfides. [PDF]
Zhang Y, Lin K, Zang Z, Chen J, Zhu T.
europepmc +1 more source
Carbonated Fluorapatite‐Gelatin‐Composites: Morphogenesis and Structure of Kniep's Dumbbells
Inspired by the pioneering work of Prof. Rüdiger Kniep on fluorapatite‐gelatin nanocomposites also known as “Kniep's Dumbbells,” this study investigates carbonated fluorapatite‐gelatin aggregates synthesized by the double diffusion technique within a gelatin gel.
Elena V. Sturm +6 more
wiley +1 more source

