C-Cl Bond Fission, Hcl Elimination, And Secondary Radical Decomposition In The 193 Nm Photodissociation Of Allyl Chloride [PDF]
The primary photodissociation dynamics of allyl chloride upon excitation at 193 nm is investigated in a crossed laser-molecular beam scattering apparatus. Tunable vacuum ultraviolet (VUV) photoionization of the products provides a unique ability to learn
Butler, L. J.+3 more
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It will be the object of this department to present each month the very latest results of investigations in the pedagogy of chemistry, to bring to the teacher those new and progressive ideas which will enable him to keep abreast of the times. Suggestions and contributions should be sent to Dr. B. S. Hopkins, University of Illinois. Urbana, III.
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Redox-Active Nanomaterials For Nanomedicine Applications [PDF]
Nanomedicine utilizes the remarkable properties of nanomaterials for the diagnosis, treatment, and prevention of disease. Many of these nanomaterials have been shown to have robust antioxidative properties, potentially functioning as strong scavengers of
Hanna, S. K.+8 more
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Vibrational Branching Ratios From The Dissociation Of The NeIBr Van Der Waals Molecule [PDF]
The degree of vibrational excitation in the IBr fragment from the vibrational predissociation of NeIBr (A (3)PI(1)) has been measured using two-color pump-probe laser-induced fluorescence spectroscopy.
Stephenson, Thomas Alex+1 more
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Is Hyperconjugation Responsible For The Gauche Effect In 1-Fluoropropane And Other 2-Substituted-1-Fluoroethanes? [PDF]
The energies and geometries of a series of 2-substituted-1-fluoroethanes were computed at the MP2/6-311++G**(6D)//MP2/6-31+G* level of theory for both the maxima and minima of the rotation about the C-C bond.
Borden, W. T.+3 more
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Second OH Overtone Excitation And Statistical Dissociation Dynamics Of Peroxynitrous Acid [PDF]
The second OH overtone transition of the trans-perp conformer of peroxynitrous acid (tp-HOONO) is identified using infrared action spectroscopy. HOONO is produced by the recombination of photolytically generated OH and NO(2) radicals, and then cooled in ...
Konen, I. M.+3 more
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High-Resolution Three-Dimensional NMR Structure Of The KRAS Proto-Oncogene Promoter Reveals Key Features Of A G-Quadruplex Involved In Transcriptional Regulation [PDF]
Non-canonical base pairing within guanine-rich DNA and RNA sequences can produce G-quartets, whose stacking leads to the formation of a G-quadruplex (G4).
Ivashchenko, S.+5 more
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Interactions Between Spermine-Derivatized Tentacle Porphyrins And The Human Telomeric DNA G-Quadruplex [PDF]
G-rich DNA sequences have the potential to fold into non-canonical G-Quadruplex (GQ) structures implicated in aging and human diseases, notably cancers.
Chen, Jessica, , \u2717+5 more
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Chemical Compositions, Fall 2013 [PDF]
The newsletter of the Department of Chemistry, published once or twice a year, highlights people, events, and facilities. Content includes brief articles on new faculty hires, faculty and staff retirements, obituaries, major facilities and equipment ...
Department of Chemistry
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