Results 101 to 110 of about 150,649 (280)

Doxorubicin (DOX) Gadolinium–Gold-Complex: A New Way to Tune Hybrid Nanorods as Theranostic Agent

open access: yesInternational Journal of Nanomedicine, 2021
Memona Khan,1 Sarah Boumati,2 Celia Arib,1 Amadou Thierno Diallo,1 Nadia Djaker,1 Bich-thuy Doan,2 Jolanda Spadavecchia1 1CNRS, UMR 7244, CSPBAT, Laboratoire de Chimie, Structures et Propriétés de Biomatériaux et d’Agents Th ...
Khan M   +6 more
doaj  

Faithful Solid State Optical Memory with Dynamically Decoupled Spin Wave Storage

open access: yes, 2013
We report an optical memory in a rare earth doped crystal with long storage times, up to 20 ms, together with an optical bandwidth of 1.5 MHz. This is obtained by transferring optical coherences to nuclear spin coherences, which were then protected ...
Ferrier, Alban   +3 more
core   +1 more source

When Light Challenges Heat: Mechanistic Insights Into a Reaction Competing With Cadogan Cyclisation in Nitro‐Perylenediimides

open access: yesChemistry – A European Journal, EarlyView.
Visible‐light irradiation of nitro‐perylenediimide in the presence of triphenylphosphine reveals an unexpected pathway competing with the classical Cadogan cyclization. Mechanistic investigations uncover the rapid and selective formation of bay‐functionalized 1‐iminophosphorane‐12‐hydroxy perylenediimide derivatives.
Manuel Pedrón Laserna   +2 more
wiley   +1 more source

Harnessing Acoustic Cavitation Energy for the Selective Degradation of Impurities in Glucose Syrup

open access: yesChemistry – A European Journal, EarlyView.
The energy released during the implosion of acoustic cavitation bubbles can be harnessed and selectively transferred to a target solute, enabling its specific decomposition without degrading other solutes present in the solution. This proof of concept was demonstrated in the degradation of impurities present in trace amount in glucose syrup.
Shambel Getachew Wasse   +2 more
wiley   +1 more source

Silicon Sheets By Redox Assisted Chemical Exfoliation

open access: yes, 2013
In this paper, we report the direct chemical synthesis of silicon sheets in gram-scale quantities by chemical exfoliation of pre-processed calcium di-silicide (CaSi2).
Ali, Mustapha Ait   +17 more
core   +3 more sources

Urothermal Synthesis of Luminescent Alkaline Earth MOFs

open access: yesChemistry – A European Journal, EarlyView.
The e‐murea derivative (1,3‐dimethylimidazolidin‐2‐one) was employed as solvent for the urothermal synthesis of a series of nine AE MOFs featuring luminescence in the crystalline state with remarkable quantum yields ranging from 0.45 to 0.84. ABSTRACT The urothermal approach in 1,3‐dimethylimidazolidin‐2‐one (e‐murea) was employed for the successful ...
Michaël Teixeira, Stéphane A. Baudron
wiley   +1 more source

The Future of Foundation Machine Learning Potentials and DFT in Homogeneous Catalysis: Competition or Synergy?

open access: yesChemistry – A European Journal, EarlyView.
Machine‐learning potentials are increasingly taking on the exploratory tasks of homogeneous catalysis, enabling rapid conformer sampling and reaction‐space mapping. However, when selectivity depends on subtle electronic effects, electronic‐structure methods remain essential.
Maxime Ferrer   +3 more
wiley   +1 more source

Cationic Permethylated Cyclodextrins Capable of Self‐Assembling Into Linear Nanostructures in Water

open access: yesChemistry – A European Journal, EarlyView.
A quaternary ammonium bridge equipped with a lipophilic substituent in permethylated cyclodextrins suppresses undesired supramolecular interactions and promotes controlled, directional head‐to‐tail self‐assembly into well‐defined linear nanostructures.
Maxime Kolb   +4 more
wiley   +1 more source

Critical phenomena: 150 years since Cagniard de la Tour

open access: yes, 2009
Critical phenomena were discovered by Cagniard de la Tour in 1822, who died 150 years ago. In order to mark this anniversary, the context and the early history of his discovery is reviewed.
A Haupt   +22 more
core   +1 more source

Ligand‐Level Chemical Activation: Coordination with Benefits

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier   +2 more
wiley   +1 more source

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