Results 41 to 50 of about 587,711 (268)
On‐Demand Deconstructable Thermosets Through Cleavable Comonomer and Thermolatent Base Synergy
Angewandte Chemie, EarlyView.Thermosets, valued for their chemical and mechanical properties, resist recycling due to their cross‐linked structure. Weak bonds via comonomers enable degradability, but diffusion limits effectiveness. We incorporate thermolatent bases before polymerization (thermal or 3D‐VAT printing).
Sophia Kouider +15 more
wiley +2 more sources
Isolable C‐Phosphonio‐Boratavinyl Anion
Angewandte Chemie, Volume 138, Issue 39, 21 September 2026.A persistent C‐phosphonio boratavinyl anion was successfully synthesized. This boron‐containing vinyl lithium, featuring a vinyl carbon with an excessively high negative charge, exhibits remarkable nucleophilic and basic character, which was demonstrated by the result of a rapid reaction with H2 at RT.
Huihui Xu +7 more
wiley +2 more sources
La chimie verte comme catalyseur de l'innovation !
, 2021 Il ne se passe pas un jour sans que l'on entende des nouvelles alarmantes sur le changement climatique ou sur le rythme insoutenable auquel le monde se développe.
Gallou, Fabrice
core
Pt Single‐Atom Catalysts on FTO for Optically Invisible pH‐Universal Hydrogen Evolution Electrodes
Advanced Energy Materials, EarlyView.Comparison of the overpotential (η) at 10 mA cm−2 in acidic electrolyte of Pt SA on FTO (this work) and other literature. ABSTRACT Transparent hydrogen‐evolution electrodes are essential for photoelectrochemical and optoelectronic energy‐conversion devices, yet typically suffer from a trade‐off between catalytic activity and optical transmission. Here,
Jihyeon Kim +8 more
wiley +1 more source
Advanced Energy Materials, EarlyView.The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti +7 more
wiley +1 more source
White‐Light‐Mediated Imidazole Catalysis Toward Terpene‐Based Thermosets
Angewandte Chemie, Volume 138, Issue 39, 21 September 2026.White‐light irradiation enables the photoinitiator‐free curing of fully bio‐based terpene epoxy–anhydride systems. A light‐induced switch in epoxide ring‐opening selectivity leads to colorless, transparent thermosets with enhanced thermomechanical performance, revealing an unexpected pathway for sustainable terpene‐based network formation.
Chenxi Zhang +3 more
wiley +2 more sources
CO2‐to‐CO Electrochemical Conversion With an Fe(I) Porphyrin Complex in Water
Angewandte Chemie, EarlyView.Using in situ UV–vis/IR spectroelectrochemistry, we track CO2 reduction by a water‐soluble iron porphyrin. Rather than the usual [Fe0] intermediate in organic solvents, CO2 binds the electrogenerated [FeI] species and undergoes reductive C─O cleavage to stable [FeII‐CO]. This previously unexplored reaction pathway is facilitated by an aqueous H‐bonding
Andrew Howe +5 more
wiley +2 more sources
Artificial Intelligence for Advanced Functional Materials: Progress and Emerging Frontiers
Advanced Intelligent Systems, EarlyView.Artificial intelligence is transforming the discovery of functional materials by linking synthesis, characterization, simulation, and design in unified workflows. Advances in machine learning, autonomous experimentation, and foundation models are accelerating innovation across energy, electronics, and biomedicine, while revealing new frontiers for ...
Cristiano Malica +38 more
wiley +1 more source
Up to 16% Optical Carbon‐13 Hyperpolarization of Donor–Acceptor Molecules at 14.1 T
Angewandte Chemie, EarlyView.Up to 16% 13C nuclear polarization is achieved using a rationally designed photo‐CIDNP polarizing agent (PA) in magic‐angle‐spinning NMR experiments at 14.1 T. The PA was designed using a combination of theoretical photocycle calculations and magnetic field dependent experiments to identify important new design principles.
Marcel Levien +10 more
wiley +2 more sources
CHIMIA, 2009 Former PhD students, post-docs and junior researchers of the Section de chimie et biochimie now holding positions at different universities and private companies remember the time they spent in Geneva and give an account of how this has set off ...
Jonathan R. Nitschke +5 more
doaj +1 more source