Results 151 to 160 of about 15,677 (253)

Spin‐Polarized Interfaces Redirect CO2 Reduction From CO to Formate

Angewandte Chemie, EarlyView.
The chiral electrocatalyst exploits the CISS effect to establish a spin‐polarized interface that selectively promotes formate production during CO2 reduction while effectively suppressing the competing hydrogen evolution. ABSTRACT Achieving high product selectivity in electrocatalytic carbon dioxide reduction (CO2RR) remains a critical challenge due to
Fan He, Xingxu Yan, Xiaoqing Pan, Yong Yan, Jing Gu   +4 more
wiley   +2 more sources

Materials Representation Learning Based on a Material–Motif Network and Heterogeneous Graphs

Advanced Intelligent Discovery, EarlyView.
Structure motifs in materials are used to construct a bipartite material–motif network that links each material to its constituent motifs and establishes connectivity among materials sharing common motifs. Network analysis reveals material clusters associated with different functional applications and supports motif‐guided screening of materials.
Anoj Aryal, Weiyi Gong, Huta Banjade, Qimin Yan   +3 more
wiley   +1 more source

Chiral laser gyroscopes breaking the lock-in limit. [PDF]

Nature
Mao YH, Xu JP, Ji HT, Yang LT, Tan ZQ, Quan YC, Pu T, Shao W, Hu JQ, Huang R, Nori F, Jing H.   +11 more
europepmc   +1 more source

Exploiting Ferroelectric and Spintronic Dynamics for Neural Network Computation

Advanced Intelligent Systems, EarlyView.
Ferroelectric and spintronic devices, relying on the control of polarization and magnetization, offer intrinsically fast, durable, energy‐efficient, and low‐latency building blocks for analog in‐memory computing. The hysteretic dynamics of an order parameter are leveraged to provide nonvolatile, multistate memory and nonlinear switching. Brain‐inspired
Dashiell Harrison, Kevin Nadaud, Josquin Harrison, Guillaume F. Nataf, Laura Bégon‐Lours   +4 more
wiley   +1 more source

Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

Angewandte Chemie, EarlyView.
Chiral supramolecular templates derived from natural amino acids direct the spatial organization of SHG‐active [Zn(SCN)4]2− units, enabling diverse second‐harmonic generation in hybrid zinc thiocyanates. ABSTRACT Chiral organic molecules have been widely used to construct hybrid nonlinear optical (NLO) materials with second‐harmonic generation (SHG ...
Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok   +6 more
wiley   +2 more sources

A NEAT Approach to Evolving Neural‐Network‐Based Optimization of Chiral Photonic Metasurfaces: Application of a NeuroEvolution‐of‐Augmenting‐Topologies Pipeline

Advanced Intelligent Systems, EarlyView.
Neuro‐evolution can boost machine‐learning optimization of chiral metasurfaces. By integrating the NEAT algorithm into a deep‐learning framework, we enable the efficient design of visible‐spectrum chiroptical responses. NEAT autonomously evolves neural‐network architectures and weights, reducing manual tuning.
Davide Filippozzi, Arash Rahimi‐Iman
wiley   +1 more source

Planar Chiral Carbazole‐Naphthalene Bisimide Hetero‐Cyclophane for Circularly Polarized Delayed Fluorescence

Angewandte Chemie, EarlyView.
Tightly stacked carbazole and 1,2:5,6–naphthalene bisimide units afforded a planar chiral hetero‐cyclophane. The architecturally refined system, with strong charge‐transfer interaction and enhanced structural rigidity, exhibits orange‐red delayed CPL emission in both solution and solid states.
Sanchari Debnath, Swadhin Garain, Yvonne Wagenhäuser, Frank Würthner   +3 more
wiley   +2 more sources

Reconfigurable chiroptical metasurface sensors enabled by bound states in the continuum. [PDF]

iScience
Liu J, Yu T, Hu H, Zhou H, Chen X, Zhan Q.   +5 more
europepmc   +1 more source

Enhancement of Dissymmetry Factors Through Axial Elongation of Hetero[n]helicenes

Angewandte Chemie, EarlyView.
A benzofuran scaffolding strategy enables the synthesis of hetero[9]‐, [12]‐, and [15]helicenes. Structural and chiroptical analyses demonstrate that systematic axial elongation increases helical distortion and significantly amplifies luminescence dissymmetry.
Jeppe S. Mogensen, Christoffer Bræstrup, Christoffer Warming, Georg I. Junker, Yann Lie, Mathias Hermann, Kurt V. Mikkelsen, Michael Pittelkow   +7 more
wiley   +2 more sources

Divergent Synthesis of Möbius and Hückel N‐Heterocycloarenes From a Common Macrocyclic Backbone

Angewandte Chemie, EarlyView.
In the divergent synthesis of Möbius and Hückel N‐heterocycloarenes from a common macrocyclic precursor, the annulation reaction dictates topology: Scholl reaction gives Möbius topology, while InCl3‐mediated alkyne annulation gives Hückel topology. The Möbius N‐heterocycloarene is unevenly contorted as revealed by crystal structure, and the Hückel N ...
Han Chen, Huishu Ma, Daiyue Yang, Zheng Zhou, Xiao Chen, Zhifeng Huang, Qian Miao   +6 more
wiley   +2 more sources