Results 121 to 130 of about 16,645 (280)

Transitioning Formamide Solvothermal Syntheses of MOFs to Less Toxic Solvents

open access: yesChemistry – A European Journal, EarlyView.
Metal‐organic Frameworks (MOFs) are commonly synthesized in toxic formamide solvents. This study investigates the synthetic factors required for effective removal of formamides across various classes of MOFs, providing a foundation for designing new sustainable MOF syntheses.
Julia C. Donovan   +2 more
wiley   +1 more source

A Short‐Cut Design Approach to Evaluate Reboiler Designs in Vapor Recompression Scenarios

open access: yesChemie Ingenieur Technik, EarlyView.
A short‐cut model framework that incorporates mechanical vapor recompression (MVR) requirements into reboiler design is presented, which is particularly beneficial during early process development with limited data or initial feasibility assessments.
Franziska Lais   +2 more
wiley   +1 more source

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova   +8 more
wiley   +1 more source

Low‐Coordination Solvation Engineering Enables Efficient and Stable Perovskite Solar Cells

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work introduces a kind of low‐coordination solvent, dimethyl carbonate (DMC), to replace a part of DMSO and DMF. DMC substitutes a part of DMSO to coordinate with PbI2 to change the chemical environment of PbI2. What is more, DMC promotes the formation of the nucleation of α‐FAPbI3 crystals.
Haokun Jiang   +4 more
wiley   +1 more source

Multifunctional ionic liquid boosts the efficiency of hole transport layer‐free carbon‐based perovskite solar cells beyond 20%

open access: yesFlexMat, EarlyView.
HTL‐free carbon‐based PSCs are promising in stability but limited by efficiency. Systematic screening identifies DMAFo as an optimized ionic‐liquid additive: the DMA+ regulates lattice distortion and relieves residual stress, while Fo‒ passivates halide vacancies, and ameliorates band‐alignment.
Zhiyang Ju   +10 more
wiley   +1 more source

Flexible white thermally activated delayed fluorescence polymer with alkyl spacer and side‐chain encapsulation for efficient solution‐processed white organic light‐emitting diodes

open access: yesFlexMat, EarlyView.
A “gemstone‐necklace” FASCE strategy synthesizes single‐component white polymers (PTF‐Qx) by alternating rigid TADF units with flexible alkyl chains. The non‐doped rigid device achieves a high EQE of 15.66% with stable white emission (CIE: 0.36, 0.46).
Wenhao Zhang   +7 more
wiley   +1 more source

Selenophene‐substituted A‐D‐A‐type non‐fullerene acceptors for organic solar cells with an ultra‐high short‐circuit current density of 27.14 mA cm−2

open access: yesFlexMat, EarlyView.
Two novel narrow bandgap electron‐deficient acceptors 6TFSe‐4F and 6TFSe‐4Cl were rationally constructed via synergistic core fluorination, selenophene substitution, and alkylation, enhancing donor‐acceptor molecular electrostatic potential difference to improve exciton dissociation and reduce energy loss.
Jianan Fang   +11 more
wiley   +1 more source

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