Results 101 to 110 of about 5,262 (281)

Synthesis of Benzopyran Atropisomers via Electrophilic Halogenation

European Journal of Organic Chemistry, EarlyView.
We report a halogenation‐based method for the synthesis of axially chiral benzopyrans, tolerating diverse substituents and halogens (Br, Cl, and I). A double bromination gives bisbenzopyrans with two stereogenic axes. Preliminary enantioselective conditions yield benzopyran atropisomer with up to 56% ee.
Alix Bourhis, Expédite Yen‐Pon, Jean Rodriguez, Damien Bonne   +3 more
wiley   +1 more source

<i>In Situ</i> Chemical Oxidation of Nonionic Organic Contaminants: The Effect of Soil Organic Matter and Minerals on Stoichiometric Efficiency. [PDF]

Environ Sci Technol
Salazar JS, Kim TK, Sedlak DL.
europepmc   +1 more source

Sufficient Gas and Solvated Ion Transport Assisted Rapid NH3 Detection at Room Temperature Through Bionic Olfactory Fibres

Exploration, EarlyView.
Bionic olfactory fibres with nanoconfined ionic liquids were developed to mimic human olfactory cilia. Benefiting from sufficient gas transport pathways provided by inter‐fibre interconnected pores and rapid transport of solvated ions in the confined nano spacing, bionic olfactory fibres show excellent sensing performance to NH3 and demonstrate the ...
Hongyang Liu, Lingyun Xu, Xiaohan Sun, Zhihao Zhao, Qi Song, Weijie Wang, Zhe Chen, Gongmo Xiang, Yupeng Chen, Fanrong Zhao, Xiangyu Jiang, Lei Jiang   +11 more
wiley   +1 more source

Flexible white thermally activated delayed fluorescence polymer with alkyl spacer and side‐chain encapsulation for efficient solution‐processed white organic light‐emitting diodes

FlexMat, EarlyView.
A “gemstone‐necklace” FASCE strategy synthesizes single‐component white polymers (PTF‐Qx) by alternating rigid TADF units with flexible alkyl chains. The non‐doped rigid device achieves a high EQE of 15.66% with stable white emission (CIE: 0.36, 0.46).
Wenhao Zhang, Hongyu Zhuang, Xinxin Ban, Shilong Feng, Tao Xu, Youqiang Qian, Shun Hu, Aiyun Zhu   +7 more
wiley   +1 more source

Nickel-catalyzed aminocarbonylation of aryl chlorides enabled by a newly designed CO source. [PDF]

Chem Sci
Liu ZW, Wang Y, A RH, Wu XF.
europepmc   +1 more source

On the Nitration of Chlorobenzene. II

NIPPON KAGAKU KAISHI, 1932
openaire   +4 more sources

Recent advances in multifunctional soft robots: A materials–structures–systems co‐design perspective for synergistic integration

FlexMat, EarlyView.
Abstract Soft robots, engineered from highly compliant materials, offer superior adaptability and safety in unstructured environments compared to their rigid counterparts. Recent advancements, fueled by bio‐inspiration and material programmability, have led to the rapid co‐evolution of their core modules: actuation, sensing, protection, energy, and ...
Qiulei Liu, Zicao Peng, Chong Sun, Haitao Yang   +3 more
wiley   +1 more source

Microwave-Assisted P-C Coupling of the Less Reactive Chlorobenzene and >P(O)H Reagents in the Absence of the Usual Mono- and Bidental P-Ligands. [PDF]

Molecules
Huszár B, Mucsi Z, Keglevich G.
europepmc   +1 more source

Reverse evolution of fluorine and side chains in bisisoindigo‐based copolymers enabling electron mobility exceeding 7 cm2·V−1·s−1

FlexMat, EarlyView.
Abstract We report the design and synthesis of a series of bisisoindigo‐based donor–acceptor (D–A) copolymers, P4F18, P4F10, P2F18, and P2F10. By reverse evolution of fluorine substitution and side‐chain structure, we effectively tuned the frontier molecular orbital energy levels, intermolecular interactions, molecular self‐assembly, and thus charge ...
Keli Shi, Chang Cui, Qianqian Zhao, Jianping Chen, Weifeng Zhang, Jiadi Chen, Qian Che, Yunchao Zhang, Youjia Li, Zhihui Chen, Liping Wang, Gui Yu   +11 more
wiley   +1 more source

Activation of Specific Reagents in Molecular Films by Sub-Ionization Electrons: Chlorobenzene/Water Films. [PDF]

Int J Mol Sci
Abdoul-Carime H, Kopyra J.
europepmc   +1 more source