Nucleophilic Aromatic Substitution in the Gas Phase
In this review, we highlight experimental studies of gas‐phase SNAr. Studying reactions in the gas phase provides invaluable information on intrinsic reactivity by eliminating the complications of solvent effects. Because SNAr is a fundamental reaction in chemical research and organic synthesis, understanding its underlying reactivity and mechanisms is
Daniel N. Hirsch +2 more
wiley +1 more source
Phytodetoxification of Lindane (γ-Hexachlorocyclohexane) With Plants Expressing a Bacterial Dechlorinase. [PDF]
De Figueras CG +6 more
europepmc +1 more source
In photosupercapacitor configurations, the supercapacitor discharges through the solar cell under dark conditions without load. If the supercapacitor voltage overcomes the threshold voltage of the cell (VSC > VON), the cell becomes forward‐biased and its impedance |Z| drops, allowing the flow of a reverse current.
Cinthia Cuevas‐Zapata +4 more
wiley +1 more source
Chiral Fjord‐Edged Nanographenes Constructed by Allylic‐Migration‐Mediated Cyclization
A novel allylic‐migration‐mediated cyclization strategy enables the construction of two fjord‐edged nanographenes without steric blocking groups. The resulting non‐planar molecules exhibit remarkable chiroptical properties, with an absorption dissymmetry factor surpassing those of pristine [5]helicene and previously reported fjord‐edged nanographenes ...
Zhen‐Lin Qiu +7 more
wiley +2 more sources
Hole migration enables efficient and ultra-bright green quantum dot LEDs. [PDF]
Zhang H +8 more
europepmc +1 more source
Abstract The Viking missions landed two spacecraft on Mars each equipped with a pyrolysis‐gas chromatograph‐mass spectrometer system capable of detecting signs of life. Although working as intended, detections of chloromethane and dichloromethane were initially attributed to terrestrial contamination.
A. Mojarro +11 more
wiley +1 more source
Comparative Effectiveness and Safety of Fluticasone-Umeclidinium-Vilanterol and Beclomethasone-Glycopyrronium-Formoterol Single-Inhaler Triple Therapies for COPD: Real-World Observational Study. [PDF]
Cherian M, Dell'Aniello S, Suissa S.
europepmc +1 more source
Beyond monofunctionality: structural perspectives on phenol oxidase side activity in a catalase
Structural and biochemical characterization of the extracellular fungal catalase ClCPO uncovers an unexpected phenol oxidase promiscuity. Crystal structures, substrate docking and electron‐transfer pathway analysis identify ligand‐binding regions and support a working mechanistic model for catalase‐associated phenol oxidase activity.Catalases are ...
Christina Ferousi +5 more
wiley +1 more source
Temporal and Partial Reversal of Airflow Limitation in Patients With COPD Treated With Single-Inhaler Long-Acting Dual Bronchodilators. [PDF]
Lu Y +10 more
europepmc +1 more source
A fully orthogonal green‐solvent strategy enables inverted layer‐by‐layer organic solar cells using water/ethanol‐soluble P(Qx8O‐T) and o‐xylene‐processed L8‐BO. Solvent‐selective deposition preserves molecular crystallinity while enabling better vertical phase separation and favorable charge transport.
Jiale Xiang +14 more
wiley +1 more source

