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Mass analyzed threshold ionization of chlorobenzene and chlorobenzene · Ar1
Chemical Physics Letters, 1997Mass analyzed threshold ionization (MATI) spectra of the 35Cl and 37Cl isotopomers of chlorobenzene have been recorded via different vibrational S1 states. Most cationic states exhibit only a small isotopic shift of 2–4 cm−1. The strongest isotope effect is observed for the 6a vibrational mode, which differs by about 6 cm−1 for the two isotopomers ...
Gerhard Lembach, Bernhard Brutschy
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SORPTION OF CHLOROBENZENES TO MINERALIZING PHYTOPLANKTON
Environmental Toxicology and Chemistry, 1993Abstract The influence of mineralization of phytoplankton (laboratory Scenedesmus spp.) on the desorption characteristics of 1,2,3,4-tetrachlorobenzene (TeCB) and hexachlorobenzene (HCB) was studied using a purge and trap method. For comparison several field samples, including a sediment, algae at different growth stages, and freeze ...
Koelmans, A.A. +2 more
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THE SULPHONATION OF CHLOROBENZENE
Canadian Journal of Research, 1948The rate of heterogeneous sulphonation of chlorobenzene in sulphuric acid solutions of different concentrations has been found to increase with amount and concentration of acid used, and with increase of temperature. No appreciable amount of sulphone was formed under the conditions used.
C. A. Winkler, H. R. Chin-Yee
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The pharmacokinetics of inhaled chlorobenzene in the rat
Toxicology and Applied Pharmacology, 1983Male rats were exposed for 8 hr/day to 100, 400, or 700 ppm of [14C]chlorobenzene vapor for either 1 or 5 days for the purpose of examining the dose dependency of parameters indicative of the toxicity process and the effect of repeated exposure. 14C burdens in the blood, liver, kidneys, lungs, and fat were measured at 0, 16, and 48 hr after exposure ...
T M, Sullivan +3 more
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Atmospheric oxidation mechanism of chlorobenzene
Chemosphere, 2014The atmospheric oxidation mechanism of chlorobenzene (CB) initiated by the OH radicals is investigated at M06-2X/6-311++G(2df, 2p) and ROCBS-QB3 levels. The oxidation is initiated by OH addition to the ortho (∼50%), para (∼33%) and meta (∼17%) positions, forming CB-OH adducts as R2, R3, and R4; while the ipso-addition is negligible (∼0.2%).
Runrun, Wu, Sainan, Wang, Liming, Wang
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Biodegradation of chlorobenzene by indigenous bacteria
Environmental Toxicology and Chemistry, 1994Abstract Soil and ground water from four sites chronically contaminated with chlorobenzenes were examined to determine whether indigenous bacteria could degrade the contaminants and whether the addition of specific chlorobenzene-degrading bacteria enhanced the degradation rate At each site, chlorobenzene-degrading bacteria were readily ...
Shirley F Nishino +2 more
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