Results 291 to 300 of about 653,033 (326)

Dual Lewis Acid Promoted/Visible Light Driven Preparation of Aryl Diazenyl Oxazoles from Isocyanoacetamides and Arylazo Sulfones

open access: yesAdvanced Synthesis &Catalysis, Volume 367, Issue 5, March 4, 2025.
Abstract While arylazo sulfones have been widely applied as arylating agents, their exploitation for diazenylation reactions has been previously limited to electron‐rich alkenes such as styrenes and silyl enol ethers. Herein we optimized a synthetic one‐pot protocol to access oxazolyl azo compounds via a selective domino ring‐closing/aryldiazenylation ...
Enzo Delalande   +5 more
wiley   +1 more source

Visible Light‐Promoted Esterification of Carboxylic Acids via Photoacid Generation Catalysis

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
A novel, environmentally friendly photochemical method for the esterification of carboxylic acids with alcohols using arylazo sulfones as photoacid generators was developed. This approach avoids traditional acidic catalysts, purification did not require chromatography and the method proved effective under continuous flow conditions for enhanced ...
Valentina Benazzi   +7 more
wiley   +1 more source

Synthesis of Spirolactones from Carbonyls via Carboborylation of N‐Sulfonylhydrazones with Alkoxycarbonylalkylboronic Acids

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Spirolactones are readily prepared from carbonyls via their N‐tosylhydrazones. The reaction involves carboborylation with ethoxycarbonyl‐substituted boronic acids, followed by oxidation and lactonization. Thermal or photochemical protocols enable versatility.
Lucía López   +3 more
wiley   +1 more source

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