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Absence of hexavalent chromium in marine carbonates: implications for chromium isotopes as paleoenvironment proxy [PDF]

open access: yesNational Science Review, 2021
AbstractThe oxygenation of Earth's atmosphere is widely regarded to have played an important role in early-life evolution. Chromium (Cr) isotopes recorded in sedimentary rocks have been used to constrain the atmospheric oxygen level (AOL) over geological times based on the fact that a positive Cr isotopic signature is linked to the presence of Cr(VI ...
Ziyao Fang, Tao Yao, Shiqiang Wei
exaly   +4 more sources

Highly fractionated chromium isotopes in Mesoproterozoic-aged shales and atmospheric oxygen [PDF]

open access: yesNature Communications, 2018
There is a long standing debate whether low atmospheric oxygen levels during the Mesoproterozoic Era hindered the evolution of crown-group animals. Here, the authors show with shale-hosted chromium isotopes that sufficient atmospheric oxygen for crown ...
Donald E. Canfield   +7 more
doaj   +2 more sources

Mechanisms of chromium isotope fractionation and the applications in the environment

open access: yesEcotoxicology and Environmental Safety, 2022
Chromium (Cr) is a toxic heavy metal that gives rise to environmental pollution and human risk. Chromium stable isotopes have a wide range of applications in both environmental field and earth science field.
Ying Li   +5 more
doaj   +3 more sources

Biogeochemical cycling of chromium and chromium isotopes in the sub-tropical North Atlantic Ocean

open access: yesFrontiers in Marine Science, 2023
Chromium (Cr) is a redox-sensitive element and because Cr isotopes are fractionated by redox and/or biological processes, the Cr isotopic composition of ancient marine sediments may be used to infer changes in past seawater oxygenation or biological ...
Rachael James   +2 more
exaly   +3 more sources

Precise measurement of chromium isotopes by MC-ICPMS. [PDF]

open access: yesJ Anal At Spectrom, 2014
We report novel analytical procedures allowing for the concurrent determination of the stable and mass-independent Cr isotopic composition of silicate materials by multiple collector inductively coupled mass spectrometry (MC-ICPMS).
Schiller M   +4 more
europepmc   +5 more sources

Method validation and geochemical modelling of chromium speciation in natural waters [PDF]

open access: yesScientific Reports
The study focuses on validating reference methods such as ICP-OES and ICP-MS for detecting ultra-trace levels of chromium in groundwater, where concentrations are typically very low.
Piotr Rusiniak   +3 more
doaj   +2 more sources

Trivalent chromium isotopes in the eastern tropical North Pacific oxygen-deficient zone [PDF]

open access: yesProceedings of the National Academy of Sciences of the United States of America, 2021
Edward A Boyle   +2 more
exaly   +2 more sources

Volatile loss following cooling and accretion of the Moon revealed by chromium isotopes [PDF]

open access: yesProceedings of the National Academy of Sciences of the United States of America, 2018
Paolo A Sossi   +2 more
exaly   +2 more sources

Determination of Trace Elements in Nickel-based High-temperature Alloy by High Resolution Plasma Mass Spectrometry [PDF]

open access: yesZhipu Xuebao, 2023
The nickel content of nickel-based high-temperature alloy is between 50% and 70%, and the alloy contents of chromium, iron, cobalt, molybdenum, aluminum, titanium and tungsten are within 20%.
HU Xuan1   +6 more
doaj   +1 more source

Summit of the N=40 island of inversion: Precision mass measurements and ab initio calculations of neutron-rich chromium isotopes

open access: yesPhysics Letters B, 2022
Mass measurements continue to provide invaluable information for elucidating nuclear structure and scenarios of astrophysical interest. The transition region between the Z=20 and 28 proton shell closures is particularly interesting due to the onset and ...
R. Silwal   +26 more
doaj   +1 more source

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