Results 261 to 270 of about 1,604,591 (318)

A Low‐Cost Curvature Detection Method for an Untethered Biped Pipeline Climbing Robot with Energy‐Efficient Strategy

open access: yesAdvanced Robotics Research, EarlyView.
A low‐cost pipeline curvature detection method has been proposed for an untethered biped pipeline surface climbing robot (BPCR) system with a five‐degree‐of freedom structure. The BPCR features adaptive vacuum suction cups equipped with multiple laser sensors on the suction modules to detect the curvature of various surfaces.
Zikang Li   +3 more
wiley   +1 more source

Biodegradation assessment tests of biopolymers in standardised water: different sources of variability. [PDF]

open access: yesBiodegradation
Gutiérrez-Rial D   +5 more
europepmc   +1 more source

Asymmetric Synthesis of Highly Substituted Spiro[2H‐pyrrole‐2,3‐Succinimide] Derivatives by Copper‐Catalyzed Post‐Ugi Reactions

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract Herein we present a novel one‐pot methodology for the synthesis of enantioenriched 2H‐pyrrolespirosuccinimides by copper‐catalyzed reactions on Ugi adducts derived from enantiopure α‐alkylbenzyl amines through a chirality transfer process. We have proposed a mechanism, supported by density functional theory (DFT) calculations, where a hydrogen
Javier Gómez‐Ayuso   +3 more
wiley   +1 more source

Synthesis of spirolactones from carbonyls via carboborylation of N‐sulfonylhydrazones with alkoxycarbonylalkylboronic acids

open access: yesAdvanced Synthesis &Catalysis, Accepted Article.
A straightforward synthesis of spirolactones from carbonyls via N‐tosylhydrazones is described. The process consist in the reaction between the N‐tosylhydrazone and ethoxycarbonylethylboronic acid or ethoxycarbonylpropylboronic acid, leading to spiro γ‐butyrolactones or δ‐valerolactones respectively. The transformation takes place by carboborylation of
Lucía López   +3 more
wiley   +1 more source

Pot‐Economical Synthesis of Fluorinated Pyrrolizinone Derivatives

open access: yesAdvanced Synthesis &Catalysis, EarlyView.
Abstract A new family of fluorinated dihydropyrrolizinones has been synthesized starting from fluorinated enamino amides and aliphatic conjugated ketones. The reaction comprises a cross metathesis reaction followed by a tandem cycloaromatization/ enamine hydrolysis/ intramolecular Friedel‐Crafts alkylation sequence.
Lidia Prieto   +6 more
wiley   +1 more source

Minimizing Energy Demand in the Conversion of Levulinic Acid to γ‑Valerolactone via Photothermal Catalysis Using Raney Ni. [PDF]

open access: yesAdv Sci (Weinh)
Bujaldón R   +8 more
europepmc   +1 more source

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