Results 11 to 20 of about 353 (134)

Lutidyl Radical Photoelectron Spectra Reveal Additive Substituent Effects on Benzyl Derivatives’ Ionization Energy

open access: yesChemPhysChem, Volume 24, Issue 20, October 17, 2023., 2023
Threshold photoelectron spectroscopy with vacuum ultraviolet synchrotron radiation and quantum chemical calculations shed new light on the ionization energies of xylyl, picolyl and lutidyl radicals. N‐ and CH3‐substituent effects on the ionization energies of benzyl‐type reactive intermediates are found to be position‐dependent and additive.
Keisuke Kanayama   +5 more
wiley   +1 more source

The Chemistry of the Cyaphide Ion

open access: yesAngewandte Chemie International Edition, Volume 62, Issue 32, August 7, 2023., 2023
128 years after the erroneously assumed synthesis of sodium cyaphide, Na(CP), and 51 years after the definitive proof of the existence of HCP, the chemistry of the cyaphide anion has finally gained momentum. This review summarizes the chemistry of the cyaphide anion, (C≡P)−, from its beginnings to the state‐of‐the art.
Tim Görlich   +5 more
wiley   +1 more source

Vibrational Predissociation Spectra of C2N− and C3N−: Bending and Stretching Vibrations

open access: yesChemPhysChem, Volume 24, Issue 15, August 1, 2023., 2023
Infrared predissociation spectra of C2N−(H2) and C3N−(H2) is reported using a cryogenic ion trap at the FELIX Laboratory, thus allowing the detection of low‐lying bending and stretching vibrations of both anions simultaneously. Vibrational configuration interaction calculations validate the assignment.
Franziska Dahlmann   +8 more
wiley   +1 more source

First Observations With a GNSS Antenna to Radio Telescope Interferometer

open access: yesRadio Science, Volume 58, Issue 8, August 2023., 2023
Abstract We describe the design of a radio interferometer composed of a Global Navigation Satellite Systems (GNSS) antenna and a Very Long Baseline Interferometry radio telescope. Our eventual goal is to use this interferometer for geodetic applications including local tie measurements.
J. Skeens   +7 more
wiley   +1 more source

The harsh environment where exoplanets live

open access: yesAstronomische Nachrichten, Volume 343, Issue 4, May 2022., 2022
Abstract The X‐ray and Extreme Ultraviolet (XUV) actvity of the Sun has determined important effects on the planets around it. In particular, high doses of X‐rays, flares, and coronal mass ejections (CMEs) combined with masses and sizes of the planets and the shielding action of the planetary magnetic fields have determined the diverse habitability of ...
Ignazio Pillitteri
wiley   +1 more source

Infrared Spectral Fingerprint of Neutral and Charged Endo- and Exohedral Metallofullerenes

open access: yesThe Astrophysical Journal Supplement Series, 2023
Small metal-containing molecules have been detected and recognized as one of the hybrid species that are efficiently formed in space, especially in the circumstellar envelopes of evolved stars.
R. Barzaga   +7 more
doaj   +1 more source

(New) molecular ions in the interstellar medium

open access: yesEPJ Web of Conferences, 2015
We summarize the present knowledge on the molecular ionic content in the interstellar medium and in circumstellar envelopes. Emphasis is given on the most recent detections and the related chemical issues.
Roueff Evelyne
doaj   +1 more source

SPECTRAL AND POLARIMETRIC STUDY OF CLOSE BINARY SYSTEMS XZ CEP AND V 448 CYG WITH A COMPOSITE SPECTRUM

open access: yesOdessa Astronomical Publications, 2017
The main parameters of the close binaries V448 Cyg and XZ Cep were determined. Computation of the chemical composition of the atmospheres of their primary components showed the existence of the hydrogen deficiency in them.
L. V. Glazunova, G. V. Manilova
doaj   +1 more source

MODELS OF CIRCUMSTELLAR MASERS IN BIPOLAR OUTFLOWS

open access: yesOdessa Astronomical Publications, 2017
Sources of molecular maser radio emission in envelopes of late-type variable stars (red giants and supergiants) are considered. Radio and optical data on asymmetry of mass loss process in red giants are briefly reviewed.
G. M. Rudnitskij
doaj   +1 more source

Vibrational, Rotational, and Electronic Spectroscopy for Possible Interstellar Detection of AlNH2 and HAlNH

open access: yesThe Astrophysical Journal, 2023
We obtained accurate vibrational frequencies, rotational constants, and vertical transition energy for AlNH _2 (X ^1 A _1 ) and HAlNH(X ^1 A′) isomers using ab initio calculations at various levels of theory.
Tarek Trabelsi   +2 more
doaj   +1 more source

Home - About - Disclaimer - Privacy