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Iodocyclization of cis-1-R-2-allylcyclopentan-1-ols

Chemistry of Heterocyclic Compounds, 1988
Derivatives of cyclopenta[b]tetrahydrofurans are formed as a result of the iodocyclization of cis-1-R-2-allylcyclopentan-1-ols. The iodocyclization reaction of unsaturated alcohols is described by a kinetic equation of the second order (the first order for each of the reagents).
Yu. I. Gevaza   +2 more
openaire   +1 more source

Synthesis of cis-1-methyl-2-aryl-3-aroylaziridines

Chemistry of Heterocyclic Compounds, 1980
trans-1-Methyl-2-aryl-3-aroylaziridines readily undergo epimerization to give the corresponding cis isomers in high yields in the presence of catalytic amounts of quaternary ammonium bases (trimethylbenzylammonium or triethylmethylammonium hydroxide). The structures of the compounds obtained were established on the basis of the IR and PMR spectra and ...
I. G. Tishchenko   +2 more
openaire   +1 more source

Preparation of some cis-1,trans-5-germacratriene derivatives

Journal of the Chemical Society D: Chemical Communications, 1971
By photoisomerisation, germacrone (I) was transformed into two photoisomers, cis-1,trans-5-germacrone (II) and cis-1,cis-5-germacrone (III): cis-1,trans-5-germacratriene (VI) was derived from (II).
Ken'ichi Takeda, I. Horibe, H. Minato
openaire   +1 more source

The Diels-Alder reaction of dienes with a cis-1-methyl group

Tetrahedron Letters, 1987
Abstract A 1,1,3-trimethyl-2-alkylbutadiene undergoes Diels-Alder reactions far more efficiently than the corresponding 1,1-dimethyl-2-alkylbutadiene.
Roger V. Bonnert, Paul R. Jenkins
openaire   +1 more source

Structural and vibrational study of the Ci(1) conformation of 18-crown-6

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2002
Optimized geometry, vibrational frequencies and IR absorption intensities were calculated for the Ci(1) conformation of 18c6. Optimized geometry was compared with the experimental geometry and that of the Ci(2) conformation of 18c6. The Ci(1) conformation is more planer than the Ci(2) conformation of 18c6, which provides an explanation that free 18c6 ...
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Cis‐1‐AIkylcycloheptandiole‐ (1, 2)

Zeitschrift für Chemie, 1968
Rolf Borsdorf, Bernd Olesch
openaire   +1 more source

Acid-catalyzed isomerization of cis-1-phenyl-1,3-butadiene and cis-1-methyl-3-phenylallyl alcohol

Journal of the American Chemical Society, 1971
Yeshayau Pocker, Martin J. Hill
openaire   +1 more source

Iterative solutions for ∑iai/λ-ci=1 equations

2010
Two new methods are proposed for solving equations of the form F(λ)=∑i=1n(ai/(λ-ci))-1=0. Both of them are simple, easy to implement, robust and reveal a super-quadratic convergence.
Leibovici, C.F., Nichita, Dan Vladimir
openaire   +1 more source

A cis-regulatory atlas in maize at single-cell resolution

Cell, 2021
Robert Schmitz   +2 more
exaly  

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