Results 21 to 30 of about 556 (101)

Persistent Mono‐Oxo Bonding with Protactinium(V) Revealed in Highly Acidic Chloride Solutions

Angewandte Chemie, EarlyView.
Protactinium(V) defies expectations. Its elusive mono‐oxo bond was revealed through a combination of extended X‐ray absorption fine structure (EXAFS) and X‐ray absorption near‐edge structure (XANES) analyses, as well as quantum chemical calculations. This bond persists even in 12 M HCl.
Melody Maloubier, Tamara Shaaban, Florent Réal, Claire Le Naour, Hanna Oher, Titouan Aubert, Pier Lorenzo Solari, Bruno Siberchicot, Rémi Maurice, Valérie Vallet   +9 more
wiley   +2 more sources

Mechanical Entropy and Its Implications

Entropy, 2001
: It is shown that the classical laws of thermodynamics require that mechanical systems must exhibit energy that becomes unavailable to do useful work. In thermodynamics, this type of energy is called entropy.
Pharis E. Williams
doaj   +1 more source

Perfect fluids

SciPost Physics, 2018
We present a systematic treatment of perfect fluids with translation and rotation symmetry, which is also applicable in the absence of any type of boost symmetry.
Jan de Boer, Jelle Hartong, Niels A. Obers, Watse Sybesma, Stefan Vandoren
doaj   +1 more source

A Perspective on Interactive Theorem Provers in Physics

Advanced Science, EarlyView.
Into an interactive theorem provers (ITPs), one can write mathematical definitions, theorems and proofs, and the correctness of those results is automatically checked. This perspective goes over the best usage of ITPs within physics and motivates the open‐source community run project PhysLean, the aim of which is to be a library for digitalized physics
Joseph Tooby‐Smith
wiley   +1 more source

Graph‐Theory Approach to Element Miscibility and Alloy Design

Advanced Science, EarlyView.
Graph and network theory enables pathway toward complex multiscale interactions between different elements for alloy design or interface engineering. Utilizing element's inherent properties and preferential interactivity, favorable mixed material formation, solubility and miscibility can be predicted.
Andrew Martin, Kien Nguyen, Sebastian Zaatini, Michael Lastovich, Bharat Gwalani, Paul Bogdan, Martin M. Thuo   +6 more
wiley   +1 more source

Cosmological FLRW phase transitions and micro-structure under Kaniadakis statistics

Physics Letters B
This article studies the thermodynamics phase transitions and critical phenomena of an FLRW cosmological model under truncated Kaniadakis's statistics. The EoS is derived from the corrected Friedmann field equations and the thermodynamics unified first ...
Joaquín Housset, Joel F. Saavedra, Francisco Tello-Ortiz   +2 more
doaj   +1 more source

What to Make and How to Make It: Combining Machine Learning and Statistical Learning to Design New Materials

Advanced Intelligent Discovery, EarlyView.
Combining machine learning and probabilistic statistical learning is a powerful way to discover and design new materials. A variety of machine learning approaches can be used to identify promising candidates for target applications, and causal inference can help identify potential ways to make them a reality.
Jonathan Y. C. Ting, Amanda S. Barnard
wiley   +1 more source

Switchable Reactivities of Metalated Phosphasilenes Regulated by Reversible 1,2‐Metal Migration

Angewandte Chemie, Volume 138, Issue 5, 28 January 2026.
We develop novel strategies for the facile synthesis of anionic phosphasilenes in the forms of both P‐metalation and Si‐metalation. The P‐metalated phosphasilene displays a pronounced π‐bond‐driven reactivity toward robust inert molecules, whereas the Si‐metalated analogue behaves as a silylene equivalent via a retro‐1,2‐silver migration.
Huaiyuan Zhu, Shicheng Dong, Xufang Liu, Xiyuan Li, Tobias Weng, Jun Zhu, Shigeyoshi Inoue   +6 more
wiley   +2 more sources

Tracking Structural and Electron Spin Density Changes in a Cooperative Mn3+ Spin Crossover Complex at Atomic Scale via Low Temperature Solid‐State NMR

Angewandte Chemie, Volume 138, Issue 3, 16 January 2026.
The spin transition of a Mn(III) complex is investigated by tracking the evolution of the 1H and 13C NMR signals of individual sites under fast low‐temperature magic angle spinning conditions. The proposed experimental methodology combined with ab initio calculations of the paramagnetic NMR shifts provides a unique toolbox to study the electronic ...
Wassilios Papawassiliou, José P. Carvalho, Subhradip Paul, Aizuddin Sultan, Michael Fardis, Georgios Papavassiliou, Grace G. Morgan, Katharina Märker, Gaël De Paëpe   +8 more
wiley   +2 more sources

Universal Entanglement and an Information‐Complete Quantum Theory

Advanced Physics Research, EarlyView.
This Perspective summarize an informationcomplete quantum theory which describes a fully quantum world without any classical systems and concepts. Here spacetime/gravity, having to be a physical quantum system, universally entangles matter (matter fermions and their gauge fields) as an indivisible trinity, and encodes information‐complete physical ...
Zeng‐Bing Chen
wiley   +1 more source