Results 151 to 160 of about 533,300 (303)

Towards a Developmental Retribution and Reciprocity Model (RRM): Implications for Youth Justice

open access: yesBehavioral Sciences &the Law, EarlyView.
ABSTRACT Youth justice systems are frequently justified by reference to developmental change, yet chronological age is often treated as a proxy for underlying psychological processes. This paper develops a Developmental Retribution and Reciprocity Model (RRM), integrating evolutionary criminology with contemporary developmental neuroscience to clarify ...
Evelyn Svingen
wiley   +1 more source

Design of experiments‐guided membrane capture facilitates integration of continuous virus inactivation using Phi6 as a surrogate virus in an intensified downstream process

open access: yesBiotechnology Progress, EarlyView.
Abstract The growing demand for cost‐efficient and flexible biomanufacturing has increased interest in process‐intensified downstream platforms. This study evaluates an intensified monoclonal antibody (mAb) purification sequence, where two unit operations traditionally performed in batch mode—Protein A capture and low pH virus inactivation (VI)—are ...
Mario Grünberg   +8 more
wiley   +1 more source

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

open access: yesChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank   +6 more
wiley   +1 more source

Versatile Palladium‐Catalyzed C‐H Arylation of Fluoroarenes with 2‐Chloropyridine Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Direct C─H arylation of fluoroarenes with 2‐chloropyridines is enabled by a simple Pd/SPhos system in isopropyl acetate. The method uses inexpensive reactants and shows broad scope and high yields. DFT computations explain reactivity and selectivity.
Federico Belnome   +6 more
wiley   +1 more source

Addition Reactions of Phosphorus‐Centered Radicals onto Olefins: Interplay Between Stability and Reactivity

open access: yesChemistry – A European Journal, EarlyView.
The energetics of the addition reaction of P‐centered radicals onto alkenes are primarily ruled by the stability of the attacking radical, as outlined by the computational screening of a wide range of reactions. In addition, donor‐acceptor substituents at the olefin have an important tuning role.
Meng Yang   +2 more
wiley   +1 more source

Energy Balancing of Electrochemical Alternatives to the Solvay Process

open access: yesChemie Ingenieur Technik, EarlyView.
To overcome the CaCl2 and CO2 emissions custom to the conventional Solvay process in soda ash production, electrochemically based alternatives were investigated. In particular, the mass‐ and energy balances for chlor‐alkali electrolysis and bipolar electrodialysis‐based processes are discussed comprehensively in the presented work.
Tom Wenzel   +3 more
wiley   +1 more source

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