Results 191 to 200 of about 82,764 (294)

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

open access: yesAngewandte Chemie, EarlyView.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu   +3 more
wiley   +2 more sources

Cobalt‐Catalyzed Intramolecular C─H Silylation of Arenes

open access: yesAngewandte Chemie, EarlyView.
Direct C─Si bond formation via C─H silylation is an atom‐economical route to organosilanes but is largely limited to noble metals. We report the first cobalt‐catalyzed intramolecular arene C–H silylation enabled by HCo(PMe3)4, which activates Si–H and C–H bonds to form diverse silacycles and silafluorenes in high yields with broad functional‐group ...
Yongqiang Xu   +4 more
wiley   +2 more sources

Multifunctional Heterogeneous Cobalt Catalyst for the One-Pot Synthesis of Benzimidazoles by Reductive Coupling of Dinitroarenes with Aldehydes in Water. [PDF]

open access: yesChemSusChem
Del Río-Rodríguez JL   +7 more
europepmc   +1 more source

Strategies Toward Accessing Enantioenriched (Hetero)Benzo‐Fused 5‐ and 6‐ Membered Rings via Intermolecular Carbometalation

open access: yesAngewandte Chemie, EarlyView.
The use of transition‐metal catalysts and design of chiral ligands have allowed chemists to access highly functionalized benzofused 5‐ and 6‐ membered rings in high yield and enantioselectivity. A common strategy used relies on an intermolecular carbometalation across alkynes and olefins, usually followed by a subsequent intramolecular carbometalation.
Clara Jans   +3 more
wiley   +2 more sources

Unraveling the Role of Alkali on Cobalt Catalyst Performance in Ethanol Steam Reforming by Operando DRIFT Studies and DFT Modeling. [PDF]

open access: yesACS Appl Mater Interfaces
Grzybek G   +10 more
europepmc   +1 more source

Improved cobalt oxide catalysts

open access: yesFocus on Catalysts, 2010
openaire   +1 more source

Water-Dispersible, Magnetically Recyclable Heterogeneous Cobalt Catalyst for C-C and C-N Cross-Coupling Reactions in Aqueous Media. [PDF]

open access: yesACS Omega
Sheikh S   +6 more
europepmc   +1 more source

Electrolyte‐Replacement‐Free Continuous Electrocatalytic Desalination Coupled With CO2 Reduction at Record Throughput and Low Cost

open access: yesAngewandte Chemie, EarlyView.
A continuous electrocatalytic desalination system powered by CO2 electroreduction that eliminates electrolyte replacement through a self‐balancing circulating design. Using a five‐chamber architecture and an efficient cobalt‐based catalyst, it achieves ultrafast salt removal, high CO production efficiency, and stable long‐term operation, offering a ...
Man Liang   +8 more
wiley   +2 more sources

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