Results 101 to 110 of about 6,725,229 (312)

A Crystalline Mono‐Coordinate Indium(I)‐Phosphaalkenyl

Angewandte Chemie, EarlyView.
The redox neutral carbometallation of a phospha‐alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono‐coordinate indium(I) compound that can reversibly extrude the phospha‐alkyne upon addition of a Lewis acid. Abstract The synthesis of the mono‐coordinate indium(I) compound In[C(Ad)═PTer] (Ad = 1‐adamantyl, Ter =
Álvaro García‐Romero, Maren Pink, Israel Fernández, Jose M. Goicoechea   +3 more
wiley   +2 more sources

Superconductivity above the lowest Earth temperature in pressurized sulfur hydride

, 2015
A recent experiment has shown a macroscopic quantum coherent condensate at 203 K, about 19 degrees above the coldest temperature recorded on the Earth, 184 K, in pressurized sulfur hydride.
Bianconi, Antonio, Jarlborg, Thomas
core   +2 more sources

Unraveling Hydride‐Driven Multiphasic Reduction Toward Tunable Germanium Structures for Lithium‐Ion Batteries

Advanced Science, EarlyView.
The sodium hydride (NaH)‐mediated reduction of germanium dioxide yields distinct Ge structures depending on the amount of reductant, revealing the dual roles of NaH in the reduction pathways. The synthesized Ge under off‐stoichiometric conditions exhibits a porous morphology and reduced crystallinity, which effectively mitigates volume expansion during
Gijung Lee, Jieun Kang, Jin Yong Kwon, Woori Bae, Noh‐Moon Lee, Byeongho Park, Yujin Park, Changwan Sun, Jihee Yoon, Hyungmin Park, Bonjae Koo, Jin Woo Yi, Jaegeon Ryu   +12 more
wiley   +1 more source

Molecular Electrocatalyst Enables Direct Electrochemical Capture and Conversion of CO2 up to Atmospheric Concentration

Angewandte Chemie, EarlyView.
A molecular manganese electrocatalyst enables the direct electrochemical capture and conversion of dilute CO2 (1% – 0.2%) to CO with nearly unit Faradaic efficiency, achieving high efficiency even at atmospheric concentrations (420 ppm). By bypassing energy‐intensive pre‐concentration steps, this integrated approach highlights a sustainable pathway for
Mattia Vettori, Federico Franco, Sergio Fernández, Guillem Pey, Vlad Martin Diaconescu, Josep M. Luis, Julio Lloret‐Fillol   +6 more
wiley   +2 more sources

Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light

Advanced Science, EarlyView.
A novel photo‐induced methodology for hydrocarbonylation has been established, resolving the inherent conflicts between competitive olefin and CO insertion in traditional methods that necessitate harsh conditions. Accordingly, an efficient and versatile hydrocarbonylation of olefins enabled by visible‐light irradiation under ambient conditions has been
Hongchi Liu, Tianze Zhang, Hanmin Huang
wiley   +1 more source

Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross‐Coupling

Angewandte Chemie, EarlyView.
Reductive cross‐couplings enable efficient C–C bond formation but are limited by the heterogeneity of Zn or costly reagents like TDAE. We report arylhydrazines as inexpensive, convenient reductants for Ni‐catalyzed sp2–sp3 coupling of aryl halides and secondary alkyl iodides. Mechanistic studies support hydrazine‐mediated NiII reduction for a NiI/NiIII
Nils Kurig, David A. Cagan, Kaid C. Harper, Yu Kawamata, Donna G. Blackmond, Phil S. Baran   +5 more
wiley   +2 more sources

A complex hydride-based electrolyte additive for rechargeable Li−S batteries

Communications Materials
Lithium−sulfur (Li−S) batteries are considered promising next-generation energy storage systems due to their high energy density, low-cost S cathodes, and potential for sustainable large-scale applications.
Sojeong Kim, Junyoung Heo, Hawon Gu, Huijeong Oh, Taegyoung Lee, Youngju Lee, Kazuaki Kisu, Shin-ichi Orimo, Jun-Woo Park, Sangryun Kim   +9 more
doaj   +1 more source

Understanding the Interplay Between Thermal Activation, Diffusion, and Phase Segregation of Molecular Dopants Blended with Polymeric Semiconductors

Advanced Electronic Materials, EarlyView.
The use of air stable but thermally labile molecules provides an efficient strategy for the N‐type doping of organic semiconductors with relatively low electron affinities. Design criteria for efficient dopants should also take into account diffusion and phase segregation that cannot be decoupled from thermally activated doping.
Francesca Pallini, Sara Mattiello, Mauro Sassi, Gabriele Paoli, Giuseppe Mattioli, Pietro Rossi, Giulia Coco, Alberto D. Scaccabarozzi, Brian Minki Kim, Pietro Mariani, Hiba Wakidi, Sadie M. Flagg, Massimiliano D'Arienzo, Mario Caironi, Thuc‐Quyen Nguyen, Luca Beverina   +15 more
wiley   +1 more source

Fabrication of Composite Cathode for All‐Solid‐State Sodium Batteries

Advanced Energy Materials, EarlyView.
The design of composite cathodes for all‐solid‐state sodium batteries must address three critical challenges—interfacial side reactions, interfacial delamination, and highly tortuous transport pathways. This work outlines structural and interfacial strategies to optimize ion transport and mechanical stability, enabling durable, and high‐performance ...
Gaoming Sun, Yuan Ma, Hehe Zhang, Shengan Wu, Shiyong Chu, Stefano Passerini, Yanjiao Ma   +6 more
wiley   +1 more source

Hydrogen Storage Capacity and Optoelectronic Response of Mechanically and Thermally Stable Lithium-Based Tetrahydrates (LiXH₄, X = B, Al, Mn), a DFT Approach

Crystals
In this work, density functional theory (DFT)-based first-principles investigations are performed by Generalized Gradient Approximation (GGA) with the Perdew–Burke–Ernzerhof (PBE) functional in the CASTEP code.
Ahmad Hussain, Nawishta Jabeen, Ali Yaqoob, Aseel Smerat, Muhammad Adnan Qaiser, Naflaa A. Aldawsari   +5 more
doaj   +1 more source