Results 131 to 140 of about 31,033 (331)

Photoinitiated Charge Transfer in a Triangular Silver(I) Hydride Complex and Its Oxophilicity [PDF]

open access: bronze, 2019
Sebastian V. Kruppa   +10 more
openalex   +1 more source

Leveraging Atomic Disorder to Modulate Hydrogen Storage Thermodynamics in Intermetallics

open access: yesInterdisciplinary Materials
Hydrogen storage in metal hydrides holds great promise for advancing a low‐carbon energy future. Yet, fine‐tuning the thermodynamics of hydrogen absorption remains challenging with traditional microalloying approaches. Here, we report a strategy inspired
Yuanyuan Shang   +8 more
doaj   +1 more source

Geminal Difunctionalization of Ketones via C─S Bond Insertion of Photogenerated Donor–Donor Diazo Compounds

open access: yesAngewandte Chemie International Edition, EarlyView.
Geminal difunctionalization of readily available building blocks provides rapid access to molecular complexity. This work introduces a strategy for installing two distinct functional groups on a carbonyl carbon by transforming it into a donor–donor diazo compound, enabling both batch and flow applications with broad solvent compatibility.
Vincent George   +13 more
wiley   +1 more source

Thermodynamic Modeling of Complex Solid Solutions in the Lu-H-N System via Graph Neural Network Accelerated Monte Carlo Simulations

open access: yesPRX Energy
Metal hydrides are important across diverse applications, such as hydrogen storage, batteries, gas sensors, nuclear reactions, and high-temperature superconductivity. Previous computational studies of metal hydrides under extreme pressures, e.g., O(10^{2}
Pin-Wen Guan   +5 more
doaj   +1 more source

A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes

open access: green, 2020
Addison N. Desnoyer   +4 more
openalex   +2 more sources

Forcing the Side‐on π‐Coordination of a C≡C Triple Bond to Technetium Using the As,CC,As Alkyne Pincer Ligand 1,2‐Bis(2‐(diisopropylarsaneyl)‐4‐(trifluoromethyl)phenyl)Ethyne

open access: yesAngewandte Chemie International Edition, EarlyView.
Technetium alkyne complexes have eluded isolation for decades with the only indicators for their existence being the isolation of vinylidene carbenes or their follow‐up reaction products despite plentiful of reports for neighboring elements. Stable, crystalline Tc(III) and Tc(V) alkyne complexes (and their Re analogs) have now been prepared and fully ...
Maximilian Roca Jungfer   +5 more
wiley   +1 more source

Microstructure and interaction in aluminum hydrides@polydopamine composites and interfacial improvement with GAP adhesive

open access: yesScientific Reports
The reduction of interfacial interaction and the deterioration of processing properties of aluminum hydrides (AlH3) is the main challenges preventing its practical application.
Qi An   +7 more
doaj   +1 more source

Colossal Barocaloric Effects in The Complex Hydride Li2B12H12 [PDF]

open access: green, 2021
Claudio Cazorla   +6 more
openalex   +1 more source

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