Results 1 to 10 of about 424 (85)
Introducing Diradicaloid Thiele's Hydrocarbon Derivatives as Ligand in Transition Metal Chemistry. [PDF]
N‐doped Thiele's hydrocarbon derivative is introduced as a ligand for the synthesis of mono‐ and bimetallic rhodium complexes as well as cyclometalated iridium complexes. These compounds constitute the first metal complexes based on a Thiele's hydrocarbon (or p‐quinodimethane) derivative and, to the best of our knowledge, the first cyclometalated ...
Mahata A, Neuman NI, Sarkar B.
europepmc +3 more sources
Fully Synthetic, Biomimicking Polysulfates With Tunable Anticoagulant and Endothelial Cell-Selective Bioactivity. [PDF]
Sulfated PHEMA‐based polyelectrolyte brushes are introduced as a reductionist platform to probe glycosaminoglycan‐inspired bioactivity. High charge density governs growth factor interactions and is associated with distinct vascular cell responses, enabling balanced endothelial and smooth muscle cell co‐culture.
Cosimi A +9 more
europepmc +2 more sources
Construction of a MOF-Based Snap-Top Delivery Nanosystem for Powerful Dual-Responsive Synergistic Colitis Treatment. [PDF]
A snap‐top delivery nanosystem based on an azobenzene metal–organic framework achieves targeted release of 6‐mercaptopurine via acid‐stable frameworks and hypoxia/pH dual‐responsive β‐cyclodextrin gates. This multifunctional platform integrates three synergistic mechanisms: precision drug delivery to inflammatory sites, intrinsic antioxidant properties
Li X +6 more
europepmc +2 more sources
Deployable 3D-Printed Vascular Stent with Surface-Catalysed Endogenous Nitric Oxide Generation. [PDF]
A deployable 3D‐printed vascular stent was fabricated with surface‐catalyzed endogenous nitric oxide generation, representing a promising new direction for stent development. The stent can be remotely controlled by magnetic force in its compressed state and fully deployed at the target site using an untethered heat source, potentially eliminating the ...
Zhou K +8 more
europepmc +2 more sources
Making Blank Faces Expressive: Chemical Approaches to the Modification of Chemically Inert Peptides. [PDF]
As an alternative to the conventional approach, which combines amino acid monomers in a one‐by‐one fashion to peptide derivatives, the chemical modification of existing peptides has attracted significant attention in recent years. However, such approaches generally target the reactive functional groups in cysteine and lysine residues, particularly in ...
Moriyama Y, Sada H, Nanjo T.
europepmc +2 more sources
Multicompartment Nanostructures as Templates for Multimetallic Hybrid Materials
ABC triblock terpolymers are promising soft templates for organic/inorganic hybrids because of their ability to form nanostructures with complex shapes, multiple compartments, and precisely localized chemistry. Exemplified on multicompartment nanofibers (
Stefanie Tjaberings +3 more
doaj +1 more source
In this article I address the question of the change in grammatical nature for the English genitive from inflectional affix to clitic. I focus on the rise of the group genitive, a construction in which the mark for possession is not attached to the head
Rodrigo Pérez Lorido
doaj +5 more sources
During the glycerol dehydration over ZSM‐5 zeolite, the modification by metal promoters results in the suppression of the bicyclic and tricyclic aromatics over the modified ZSM‐5 zeolite catalysts. However, the issue of the fast deactivation still remains an apparent challenge, which requires more different perspectives to understand the deactivation ...
Yonghua Yu +7 more
wiley +1 more source
This work provides insight into the photoluminescence mechanism of nitrogen‐doped carbon dots derived from PTCDA and urea. The materials exhibit a dual‐emission system composed of dominant, excitation‐independent core emission and secondary excitation‐dependent surface/state emission.
Mariel Escobal +5 more
wiley +1 more source
Luminescent Hydrogen‐bonded organic frameworks (HOFs) provide an innovative platform for sensing and optoelectronic applications. This review outlines design principles, recent advances in synthesis and optical tuning, diverse sensing applications, and discusses current challenges and future directions for HOFs.
Heng Wu +4 more
wiley +1 more source

