Results 171 to 180 of about 51,006 (322)

A Mononuclear Scenario for the Copper‐Catalyzed Monooxygenation of Phenolic Substrates

open access: yesChemistry – A European Journal, EarlyView.
ABSTRACT Whereas a dinuclear pathway applies to the monooxygenation of phenols by the type 3 copper enzyme tyrosinase, a mononuclear pathway has been identified for the same reaction in corresponding small‐molecule systems. DFT calculations of five copper model complexes reveal that the latter mechanism is energetically feasible, identifying all ...
Alexander Koch   +3 more
wiley   +1 more source

Ultra‐Wideline 2D Correlations Among Low‐γ Species in Solid‐State NMR via the Progressive Saturation of a Common Proton Reservoir

open access: yesChemistry – A European Journal, EarlyView.
This study introduces PROSPECT, a 2D solid‐state NMR method that correlates MHz‐wide, low‐γ anisotropic powder patterns. PROSPECT operates by progressively depleting a shared 1H dipolar‐order reservoir via two independently stepped cross‐polarizing offsets, yielding homonuclear and heteronuclear correlations without requiring direct transfers or even ...
Rihards Aleksis, Lucio Frydman
wiley   +1 more source

Fully Reversible Regulation of 8‐17 DNAzyme Activity Using Nucleoside‐Based Diarylethenes

open access: yesChemistry – A European Journal, EarlyView.
The site‐specific incorporation of nucleosidic diarylethenes into the 8–17 deoxyribozyme (DNAzyme) identified position 2.1 as optimal. Compound dU‐PhtBu enabled efficient light‐dependent control of catalytic activity, while maintaining thermal stability and reversibility.
Jörn Bargstedt   +3 more
wiley   +1 more source

Mechanical Vapor Recompression in Distillation: A Framework to Analyze Technical Feasibility, Economic Competitiveness, and Ecological Benefits

open access: yesChemie Ingenieur Technik, EarlyView.
Communication: An approach for a holistic evaluation of distillation processes with mechanical vapor recompression combining an initial energy potential analysis, shortcut methods for the compressor and reboiler design, and the determination of economic and ecological performance parameters is presented.
Katharina Jasch   +4 more
wiley   +1 more source

Correlative Electron Paramagnetic Resonance Imaging and Atomic Force Microscopy of Lithium Deposited on Copper

open access: yesChemPhysChem, Volume 26, Issue 6, March 15, 2025.
The correlation of a spectroscopic (EPRI) and microscopic (AFM) technique is demonstrated for a sample of Li deposited on Cu. Areas of different morphology were analysed. The techniques complement each other's length scales as well as the information obtained from the sample.
Beatrice Wolff   +5 more
wiley   +1 more source

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