Results 161 to 170 of about 2,452 (216)

Excited‐State Antiaromaticity in Nonbenzenoid Aromatics: Examining the Dynamics of Intramolecular Proton Transfer With a Small Driving Force

open access: yesAngewandte Chemie, EarlyView.
The excited‐state antiaromaticity of hydroxybenzotropyliums (HBTs) can be tuned through substituent effects to bring the aromatic ‘enol’ (E) and keto (K) tautomers close in energy. This leads to abnormally slow excited‐state proton transfer (on the ns timescale), giving rise to dual fluorescence emission and weak photoacidity.
Promeet K. Saha   +6 more
wiley   +2 more sources

Experimental realization of dice-lattice flat band at the Fermi level in layered electride YCl. [PDF]

open access: yesNat Commun
Geng S   +17 more
europepmc   +1 more source

The Interplay of Magnetic Order with the Electronic Scattering and Crystal-Field Effects in a Metallic Ferromagnet. [PDF]

open access: yesAdv Sci (Weinh)
Shee P   +11 more
europepmc   +1 more source

Enhanced two-dimensional ferromagnetism in van der Waals β-UTe<sub>3</sub> monolayers. [PDF]

open access: yesSci Adv
Thomas SM   +14 more
europepmc   +1 more source

Perilipin‐2‐Anchored Lipid Droplet‐Targeting Phototheranostics

open access: yesAngewandte Chemie, EarlyView.
This study reports two NIR theranostic dyes, C‐BDP‐OH and C‐BDP‐OMe. C‐BDP‐OMe targets lipid droplets via a dual‐anchoring mechanism with PLIN2, enabling wash‐free tumor imaging. With 62.6% photothermal conversion efficiency, it achieves tumor ablation by downregulating PLIN2, disrupting LD‐mitochondria crosstalk, and triggering apoptosis and ...
Lipeng Zhang   +9 more
wiley   +1 more source

A UHV-compatible, time-resolved spontaneous Raman spectrometer for multi-messenger ultrafast studies: Design and applications to photoinduced dynamics. [PDF]

open access: yesStruct Dyn
Finardi AM   +11 more
europepmc   +1 more source

Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement

open access: yesAngewandte Chemie, EarlyView.
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone   +8 more
wiley   +1 more source

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