The excited‐state antiaromaticity of hydroxybenzotropyliums (HBTs) can be tuned through substituent effects to bring the aromatic ‘enol’ (E) and keto (K) tautomers close in energy. This leads to abnormally slow excited‐state proton transfer (on the ns timescale), giving rise to dual fluorescence emission and weak photoacidity.
Promeet K. Saha +6 more
wiley +2 more sources
Experimental realization of dice-lattice flat band at the Fermi level in layered electride YCl. [PDF]
Geng S +17 more
europepmc +1 more source
The Interplay of Magnetic Order with the Electronic Scattering and Crystal-Field Effects in a Metallic Ferromagnet. [PDF]
Shee P +11 more
europepmc +1 more source
Quantum metric-induced giant and reversible nonreciprocal transport phenomena in chiral loop-current phases of kagome metals. [PDF]
Tazai R +3 more
europepmc +1 more source
Enhanced two-dimensional ferromagnetism in van der Waals β-UTe<sub>3</sub> monolayers. [PDF]
Thomas SM +14 more
europepmc +1 more source
Perilipin‐2‐Anchored Lipid Droplet‐Targeting Phototheranostics
This study reports two NIR theranostic dyes, C‐BDP‐OH and C‐BDP‐OMe. C‐BDP‐OMe targets lipid droplets via a dual‐anchoring mechanism with PLIN2, enabling wash‐free tumor imaging. With 62.6% photothermal conversion efficiency, it achieves tumor ablation by downregulating PLIN2, disrupting LD‐mitochondria crosstalk, and triggering apoptosis and ...
Lipeng Zhang +9 more
wiley +1 more source
A UHV-compatible, time-resolved spontaneous Raman spectrometer for multi-messenger ultrafast studies: Design and applications to photoinduced dynamics. [PDF]
Finardi AM +11 more
europepmc +1 more source
Redirecting Excited‐State Proton Transfer Through Supramolecular Polymerization in Nanoconfinement
Supramolecular confinement redirects the excited‐state proton transfer pathway of an amphoteric emitter. In water, the molecule undergoes ESPD, whereas co‐assembly with γ‐cyclodextrin forms nanotubes that template slip‐stacked emitter pairs and enable ESIMPT. Structural and photophysical characterization of the assemblies shows that the preorganization
Luis C. Pantaleone +8 more
wiley +1 more source
Disentangle Intertwined Interactions in Correlated Charge Density Wave with Magnetic Impurities. [PDF]
Park JW, Kim H, Yeom HW.
europepmc +1 more source

