Interpretation of Dielectric Properties for Materials showing Constant-Phase Element (CPE) Impedance Response [PDF]
Abstract not Available.
Orazem M.E. +9 more
core +14 more sources
Network Model of the CPE [PDF]
Analysis of fractal systems (i.e. systems described by fractional differential equations) necessitates to create an electrical analog model of a crucial subsystem called Constant Phase Element (CPE).
J. Valsa, P. Dvorak, M. Friedl
doaj +2 more sources
The influence of sintering condition on microstructure, phase composition, and electrochemical performance of the scandia-ceria-Co-doped zirconia for SOFCs [PDF]
Samples of 6 mol% Sc2O3 - 1 mol% CeO2 co-doped ZrO2 were fabricated by conventional ceramic processing methods and sintered at various temperatures from 1000 to 1650°C in air.
Elahi Pooya +3 more
doaj +1 more source
Simple circuit equivalents for the constant phase element.
The constant phase element (CPE) is a capacitive element with a frequency-independent negative phase between current and voltage which interpolates between a capacitor and a resistor.
Sverre Holm +2 more
doaj +1 more source
Considering literature of electrochemical impedance spectroscopy (EIS) it was discovered that for calculation of the value of double-layer capacitance (Cdl) from the constant phase element (CPE) two equations, with or without solution resistance (Rs ...
Vladimir D. Jović
doaj +1 more source
On the use of a constant phase element (CPE) in electrochemistry
Several techniques can be used to experimentally determine the interfacial capacitance of an electrode, which is a crucial parameter used for quantifying the efficiency of supercapacitors. However, the values obtained from cyclic voltammetry can be significantly different from those extracted from electrochemical impedance spectroscopy analysis.
Gateman, Samantha +5 more
openaire +2 more sources
Difference between Charge–Voltage Relations of Ordinary and Fractional Capacitors
In an ordinary time-varying capacitor, there is debate on whether a time-domain multiplication or a time-domain convolution of capacitance and voltage determines charge.
Eirik Brenner Marthins, Sverre Holm
doaj +1 more source
Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 2. Capacitance [PDF]
Finite–element simulations were performed to determine the influence of a radial distribution of capacitance on the impedance of ideally polarized disk electrodes. The characteristic length associated with this form of distribution was found to be the period of the distribution.
Alexander, Christopher L. +2 more
openaire +2 more sources
Contribution of Surface Distributions to Constant-Phase-Element (CPE) Behavior: 3. Adsorbed Intermediates [PDF]
Abstract The influence of surface distributions on rates of heterogeneous reactions coupled by adsorbed intermediates was studied to determine whether this form of surface heterogeneity can provide a physical explanation for constant-phase-element behavior.
Department of Chemical Engineering, University of Florida,Gainesville, FL, USA ( host institution ) +4 more
openaire +2 more sources
Constant Phase Element in the Time Domain: The Problem of Initialization
The constant phase element (CPE) is found in most battery and supercapacitor equivalent circuit models proposed to interpret data in the frequency domain.
Juan Antonio López-Villanueva +1 more
doaj +1 more source

