Results 191 to 200 of about 1,834,557 (260)

Molecularly Templated Buried Interfaces for Inverted Perovskite Solar Cells

open access: yesAngewandte Chemie, EarlyView.
We demonstrate a molecularly matched buried interface between SAM and perovskite, enhancing adhesion and passivating defects. This optimized interface achieves 26.58% power conversion efficiency and 86.72% fill factor with exceptional operational stability in both large‐area and wide‐bandgap devices, thereby increasing efficiency and prolonging ...
Songyang Yuan   +19 more
wiley   +2 more sources

A Mechanical sp2‐Jail for C60 Fullerene

open access: yesAngewandte Chemie, EarlyView.
A rigid bisporphyrin receptor with an exceptionally compact 3D cavity functions as a molecular “mechanical jail”, tightly enclosing C60 fullerene. Near‐perfect shape complementarity affords ultrahigh binding affinity while imposing a large kinetic barrier for guest exchange, rendering encapsulation effectively irreversible under ambient conditions ...
A. Priscila Gia   +8 more
wiley   +2 more sources

1,4‐Brook Rearrangement of β‐Silyl Allylic Alcohols: Trisubstituted Alkenes by Copper‐Mediated Stereoretentive ipso‐Substitution Reactions

open access: yesAngewandte Chemie, EarlyView.
To fully leverage the power of the ruthenium‐catalyzed trans‐hydrosilylation of propargyl alcohols, it was necessary to develop a practical and robust method for the activation of those products that carry the silyl group distal to the hydroxy substituent.
Paul Haf‐Moths   +2 more
wiley   +2 more sources

Revisiting Coulombic Efficiency Paradigm: Electrolyte Additive Design for Lithium Metal Batteries

open access: yesAngewandte Chemie, EarlyView.
Coulombic efficiency (CE) is a key metric for screening advanced electrolyte formulations for rechargeable batteries. Combined with interphasial characterizations, statistical analyses of CE data uncover the synergistic interaction between fluorinated additives and salt anions, enabling more precise correlations of chemical functionalities with ...
Qixin Wang   +16 more
wiley   +2 more sources

Rational Design of a Synthetic Galliphore for the Diagnostic Nuclear Imaging and Treatment of Bacterial Infections

open access: yesAngewandte Chemie, EarlyView.
KO‐NH2 is a synthetic metallophore that preferentially binds Ga3+ over Fe3+ and is recognized by bacterial transporters. Photocrosslinking identifies CirA and Fiu as key uptake proteins in E. coli. KO‐NH2 enables targeted imaging and treatment of E. coli soft tissue infections.
Phuong Nguyen Tran   +5 more
wiley   +2 more sources

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