Results 151 to 160 of about 15,592 (253)

Polycarbonate Vitrimers and Dynamic Co‐Networks From Epoxide/Carbon Dioxide Copolymerization

open access: yesMacromolecular Rapid Communications, EarlyView.
This work demonstrates how CO2‐derived poly(propylene carbonate) and poly(cyclohexene carbonate) backbones influence vitrimer thermo‐mechanical behavior. By tuning backbone composition, epoxide crosslinker chemistry and blend ratios, the crosslinked materials span a wide property window, from highly extensible to stiff, glassy networks, establishing an
Satej S. Joshi   +3 more
wiley   +1 more source

Biocompatible Sulfobetaine Polymer‐Artemisinin Conjugates Inducing Ferroptosis in Cancer Cells: Synthesis by Mechanochemical Solid‐State Polymerization and Characterization

open access: yesMacromolecular Rapid Communications, EarlyView.
The amphiphilic copolymer incorporating a hydrophobic chain conjugated with artesunate into a biocompatible sulfobetaine polymer is synthesized by solid‐state copolymerization of sulfobetaine methacrylate and methacrylamide derivative conjugating artesunate.
Naoki Doi   +9 more
wiley   +1 more source

Temperature‐Driven Switching Between Block, Near‐Statistical, and Gradient Copolymers Enabled by Multinuclear Aluminum Catalysis

open access: yesMacromolecular Rapid Communications, EarlyView.
A single multinuclear aluminum catalyst enables temperature‐driven switching between block‐enriched, near‐statistical, and gradient CL/LA copolymer microstructures. Modulation of propagation and exchange processes within one catalytic platform provides a unified kinetic–thermodynamic framework for sequence control in biodegradable polyester ...
Yoseph Kim   +4 more
wiley   +1 more source

Exploring 2‐D σ−σ* Conjugation in Cyclic Polysiloxane Copolymers

open access: yesMacromolecular Rapid Communications, EarlyView.
We find σ−σ * conjugation in copolymers synthesized by reacting the cyclomer [vinylMeSiO]4 in a 1:1 ratio with various Br‐Ar‐Br. Further, on modifying the remaining unsubstituted viny groups with Br‐Ar’, we change the main chain photophysics. However, as a test, we also appended Br‐Ar’ groups on the cylomer alone observing σ−σ * conjugation coincident ...
Zijing Zhang   +5 more
wiley   +1 more source

Development of a novel dismantlable adhesive for orthodontic use triggered by thermal stimulation. [PDF]

open access: yesSci Rep
Shundo A   +12 more
europepmc   +1 more source

Synthesis of Borneol‐Polymers as Fluorescent Sensors for Pollutant Detection

open access: yesMacromolecular Symposia, EarlyView.
ABSTRACT In this work, a borneol‐derived monomer was employed to synthesize two novel copolymers, poly(vinyl acetate‐co‐bornyl methacrylate) (CopBM‐1) and poly(p‐acryloyloxybenzaldehyde‐co‐bornyl methacrylate) (CopBM‐2), via radical copolymerization. Both copolymers demonstrated aggregation‐induced emission in DMF at concentrations exceeding 0.04 wt.%.
Viorica‐Elena Podasca   +2 more
wiley   +1 more source

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