Results 241 to 250 of about 83,698 (348)

A PLP‐SEC Investigation of Di(Ethylene Glycol) Methyl Ether Methacrylate Radical Polymerization Propagation Kinetics in Solution

open access: yesMacromolecular Reaction Engineering, EarlyView.
The propagation rate coefficient of di(ethylene glycol) methyl ether methacrylate exhibits the same temperature dependency but is a factor of 12 higher in aqueous solution compared to bulk. Smaller increases are observed in ethanol and ethanol/water mixtures, with the value of the rate coefficient decreasing as the monomer concentration in solution is ...
Fatemeh Salarhosseini   +1 more
wiley   +1 more source

Quantification of Homopolymer Impurities in Structured Acrylate Copolymers Produced by High‐Temperature Semi‐Batch Radical Polymerization

open access: yesMacromolecular Reaction Engineering, EarlyView.
Isobornyl acrylate macromonomer solutions are synthesized via high‐temperature radical polymerization using a starved‐feed semi‐batch operating policy. Through sequential feeding, the macromonomer solution functions as an addition‐fragmentation agent, facilitating the production of blocky and comb acrylate copolymers.
Elizabeth G. Bygott   +3 more
wiley   +1 more source

Modeling n‐Butyl Acrylate Polymerization using Complementary Modeling Techniques

open access: yesMacromolecular Reaction Engineering, EarlyView.
Two different simulation methods are used for the radical polymerization of nBA: deterministic in Predici and stochastic with mcPolymer. It has been successfully implemented across a wide temperature range. It turns out that the partially different implementation of chain‐length‐dependent termination and β‐scission are important for obtaining ...
Marco Drache   +3 more
wiley   +1 more source

Polyvinylidene Fluoride: Reaction Engineering and Applications

open access: yesMacromolecular Reaction Engineering, EarlyView.
An updated review on polyvinylidene fluoride (PVDF) is presented in this work. Its properties, important areas of application and different methods of production are described, with particular focus on emulsion polymerization, covering the latest advances in formulations and modeling studies.
Burak Hanamirian   +2 more
wiley   +1 more source

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