Results 111 to 120 of about 38,732 (245)

Side‐Chain‐Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin‐State Regulation for Photocatalytic CO2 Reduction

Advanced Materials, EarlyView.
Alkoxy chain length drives a continuous transition from eclipsed AA to a serrated, slipped AA* configuration over Co‐porphyrin COFs. A moderate slip both contracts the pore channel to enrich CO2 and suppress hydrogen evolution, and enhances collective high‐spin of Co sites, which delivers a record CO production rate with high selectivity.
Jie He, Qingxuan Chen, Minxian Zhang, Wenhao Zhao, Aoni Xu, Jinqiang Zhang, Hongqi Sun, Shaobin Wang, Xiaoguang Duan   +8 more
wiley   +1 more source

Decoding Synergistic Pathways in Bimetallic MOFs for Advanced Oxidation Processes

Advanced Materials, EarlyView.
This review presents a unified framework linking metal pairing and framework design with electronic structure, redox cycling, oxidant activation, reactive‐species generation, and catalytic performance across photocatalytic and oxidant‐based BMOF‐AOPs. The resulting design principles guide the development of hydrolytically stable and efficient BMOFs for
Karim El‐Naggar, Huayang Zhang, Shaobin Wang   +2 more
wiley   +1 more source

Open-air green-light-driven ATRP enabled by dual photoredox/copper catalysis. [PDF]

Chem Sci, 2022
Szczepaniak G, Jeong J, Kapil K, Dadashi-Silab S, Yerneni SS, Ratajczyk P, Lathwal S, Schild DJ, Das SR, Matyjaszewski K.   +9 more
europepmc   +1 more source

Spatial‐Compatibility‐Assisted Molecular Intercalation in MXenes

Advanced Materials, EarlyView.
This work demonstrates a solvent–free NH4F–mediated route for simultaneous Al removal and molecular intercalation in MXenes. Intercalants are selected by comparing their crystallographic X, Y, and Z dimensions with the MXene interlayer spacing, establishing a spatial‐compatibility criterion that rationalizes guest–host matching and enables predictive ...
Minhao Sheng, Xiaoqing Bin, Xiangyang Liu, Yingji Zhao, Wenxiu Que, Yusuke Asakura, Yusuke Yamauchi   +6 more
wiley   +1 more source

Copper-based oxidation catalysis [PDF]

Acta Crystallographica Section A Foundations of Crystallography, 2010
T. J. Muller, G. Steyl, A. Roodt
openaire   +1 more source

Bifunctional Catalysis Drives Efficient and Ethanol‐Producing Aqueous Zn‐CO2 Batteries

Advanced Materials, EarlyView.
A unified bifunctional catalyst breaks the trade‐off between CO2 reduction and O2 evolution, delivering high efficiency, ethanol production, and long‐term stability in Zn‐CO2 batteries while revealing degradation pathways for next‐generation bifunctional electrocatalysts.
Divyani Gupta, Jinshuo Zou, Anoja Kawsihan, Jodie A. Yuwono, Zhaoliang Wu, Jun Yu, Yameng Fan, Sailin Liu, Jianfeng Mao, Zaiping Guo   +9 more
wiley   +1 more source

Azetidine synthesis enabled by photo-induced copper catalysis via [3+1] radical cascade cyclization. [PDF]

Innovation (Camb), 2022
Li J, Yu L, Peng Y, Chen B, Guo R, Ma X, Xue XS, Liu Y, Zhang G.   +8 more
europepmc   +1 more source

Spectrally Coordinated Plasmonic–Photothermal Photocatalysts for Mineralization of Mixed Indoor VOCs Under White LED Illumination

Advanced Materials, EarlyView.
A plasmonic–photothermal–photocatalytic hybrid comprising Cu(II)‐grafted TiO2, yolk–shell Au@SiO2, and reduced graphene oxide sheets (CuT/AuSi‐GS) harvests full‐spectrum white light‐emitting diode (LED) light via complementary photocatalytic oxidation, localized surface‐plasmon‐resonance‐induced electric‐field enhancement, and photothermal acceleration.
Minhyung Lee, Geun Young Kim, Gahye Shin, Haein Cho, Juwon Lee, Jinglin Wen, Wooyul Kim, Changha Lee, Kangwoo Cho, Jae‐Hyuk Kim, Hyoung‐il Kim   +10 more
wiley   +1 more source

Combining visible-light induction and copper catalysis for chemo-selective nitrene transfer for late-stage amination of natural products. [PDF]

Commun Chem, 2022
Xing Q, Jiang D, Zhang J, Guan L, Li T, Zhao Y, Di M, Chen H, Che C, Zhu Z.   +9 more
europepmc   +1 more source

Atom–Cluster Synergy in Scalable Fe–Ru Dual‐Site Architectures Accelerates Alkaline Hydrogen Evolution

Advanced Materials, EarlyView.
A mechanochemically synthesized dual‐site electrocatalyst (RuNC@Fe1NC) accelerates alkaline hydrogen evolution via atomic‐level spatial decoupling. Oxophilic Fe single atoms effectively dissociate water, while adjacent Ru nanoclusters rapidly recombine hydrogen.
Jae‐Hoon Baek, Seong Hyeon Kweon, Sun Gwan Cha, Se Jung Lee, Jinwoo Baek, Dong Hyeok Kwon, Hojeong Lee, Youngkook Kwon, Sang Kyu Kwak, Jong‐Beom Baek   +9 more
wiley   +1 more source