Results 141 to 150 of about 6,752 (248)

Single‐Atom Control of Aromaticity and Excited‐State Dynamics in Endohedral Zirconium–Antimony Zintl Clusters

open access: yesAngewandte Chemie, EarlyView.
Single‐atom growth from [Zr@Sb12]2− to [Zr@Sb13]3− disrupts the closed‐shell S2P6 superatomic configuration and markedly attenuates three‐dimensional (3D) aromaticity. Ultrafast spectroscopy further links stronger spherical aromaticity to slower excited‐state relaxation, establishing an atom‐resolved structure‐aromaticity‐dynamics relationship ...
Yun Zhang   +7 more
wiley   +2 more sources

A Colloidal Quantum Dot Thermistor and Bolometer. [PDF]

open access: yesAdv Mater
Kumar G   +7 more
europepmc   +1 more source

Semiconducting Covalent Organic Frameworks Based on Spin‐Delocalized Trioxotriangulene Neutral Radicals

open access: yesAngewandte Chemie, EarlyView.
Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla   +8 more
wiley   +2 more sources

Acceptor‐Doped Cerium Oxides Enabling Metallic Nanocatalyst Exsolution for Hydrogen Production From Ammonia

open access: yesAngewandte Chemie, EarlyView.
Outstanding catalytic results for NH3 decomposition for H2 production were obtained with metallic Ru, Rh, and RuRh nanoparticle‐exsolved CeO2‐based catalysts. Significant lower amounts of available superficial metallic fractions were needed in comparison to conventional Ru‐impregnated materials.
Andrés López‐García   +8 more
wiley   +2 more sources

Hole migration enables efficient and ultra-bright green quantum dot LEDs. [PDF]

open access: yesNat Commun
Zhang H   +8 more
europepmc   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie   +11 more
wiley   +2 more sources

Quantum Dot Solar Cells: Background, Progress, and Perspective. [PDF]

open access: yesMicromachines (Basel)
Neupane K   +6 more
europepmc   +1 more source

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