Results 151 to 160 of about 657,206 (216)

Myrcene‐Based Tailored Co‐Polymers as Active Pharmaceutical Excipients: Bio‐Based Solutions for Mucoadhesive Excipients

open access: yesAdvanced Functional Materials, EarlyView.
Mucoadhesive amphiphilic block and statistical copolymers were synthesized via Reversible Addition–Fragmentation Chain Transfer polymerization from bio‐sourced myrcene and polyethylene glycol methacrylate. The resulting polymers exhibit narrow molar‐mass distributions, high regioselectivity, well‐defined microstructures, and tend to self‐assemble into ...
David Gintsburg   +9 more
wiley   +1 more source

Engineering MnNiPx Cathode via Dual Role of Mn: Simultaneous Enhancement of Activity and Intermittent Operation Durability

open access: yesAdvanced Functional Materials, EarlyView.
Engineering MnNiPx cathodes through the dual role of Mn simultaneously improves hydrogen evolution reaction activity and intermittent‐operation durability. Mn preferentially oxidizes to protect Ni–P sites from irreversible oxidation, while metallic Mn incorporation enhances the HER kinetics of Ni–P active layer.
Ik‐Sun Kim   +16 more
wiley   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Bio‐Inspired Synthesis of Macroporous Single Crystal Particles as Scattering Agents

open access: yesAdvanced Functional Materials, EarlyView.
A general strategy is presented that delivers unique, single‐crystal microparticles that combine submicron macroporosity and uniform particle shapes. A bioinspired approach is used to occlude three distinct types of additives – polystyrene microspheres, polymer vesicles and amino acids – within calcite single crystals, and subsequent thermal annealing ...
Stephanie E. Foster   +11 more
wiley   +1 more source

Nano‐Scale Characterization of Impurities Segregation in Solid Oxide Electrolysis Cells

open access: yesAdvanced Functional Materials, EarlyView.
Cathodic polarization induces impurity segregation in Ni, forming an amorphous Na─Al─Si─O amorphous phase at grain boundaries. Under ultralow oxygen partial pressure, multiple elements dissolve, migrate, and reoxidize within the metal. A patterned model system provides direct nanoscale evidence, clarifying the mechanism of polarization‐driven impurity ...
Zhongtao Ma   +5 more
wiley   +1 more source

General Synthesis of Amorphous Pd‐Based Nanoparticles Towards Highly Efficient Nitrate‐to‐Ammonia Electrocatalysis

open access: yesAdvanced Functional Materials, EarlyView.
A family of amorphous palladium‐based multi‐component phosphides nanoparticles, synthesized via a robust one‐step wet‐chemical method, overcoming the immiscibility of different elements and the difficulty in forming a stable, disordered structure. When applied in the electrochemical nitrate reduction reaction, these nanocatalysts effectively suppress ...
Lei Xu   +20 more
wiley   +1 more source

Electrolyte‐Induced Cu+ Preservation Results in a Selectivity Switch of Electrocatalytic CO2 Reduction at a Copper‐Organic Framework as Electrocatalyst

open access: yesAdvanced Functional Materials, EarlyView.
The active role of KCl as a neutral electrolyte enables switching the selectivity on a Cu organic framework from C1 to C2+ products during electrocatalytic CO2 reduction. ABSTRACT We introduce a copper‐nicotinate (Cu‐NA) framework as a halogenide‐stabilized Cu+/Cu0 pre‐catalyst for electrocatalytic CO2 reduction with high C2+ selectivity in a “neutral”
Anirudha Shekhawat   +11 more
wiley   +1 more source

Redirecting Nano‐Silicon Agglomeration: Dual‐Carbon Design Triggers Self‐Adaptive Nanoporous Si Sponge for Enhanced Lithium Storage

open access: yesAdvanced Functional Materials, EarlyView.
This study addresses silicon anode degradation using an engineered nSi/Gr/C dual‐carbon matrix. By restricting SEI infiltration, the architecture redirects silicon agglomeration into a beneficial structural self‐adaptive activation. During cycling, silicon nanoparticles self‐organize into a resilient nanoporous sponge. This dynamic network accommodates
Wei Zhang   +7 more
wiley   +1 more source

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