Dimensional evolution of charge mobility and porosity in covalent organic frameworks
Covalent organic frameworks are an emerging class of covalently linked polymers with programmable lattices and well-defined nanopores. Developing covalent organic frameworks with both high porosity and excellent charge transport properties is crucial for
Shuai Fu +8 more
doaj +1 more source
Covalent-organic frameworks (COFs) and metal-organic frameworks (MOFs) have been a promising carrier for drug delivery because of excellent biocompatibility, developed porous structure and sufficient interactions of host-guest molecules.
Yuhao Sheng, Kunfang Ma
doaj +1 more source
Photo‐Degradable Polyester Networks and Multi‐Photon Printed Objects Based on Cyclic Ketene Acetals
The current work introduces a photoreversible polyester network derived from radical ring‐opening polymerization of cyclic ketene acetals. It combines photoreversible cross‐linking with initiator‐free multi‐photon printing. Reversible network formation, tunable mechanical properties, and selective degradation highlight its potential as a versatile ...
Till Meissner +5 more
wiley +1 more source
Identification of Two-Dimensional Covalent Organic Frameworks with mcm Topology and their Application in Photocatalytic Hydrogen Evolution [PDF]
Covalent organic frameworks have attracted considerable attention in recent years as a distinct class of crystalline porous organic materials. Their functional properties are inherently linked to their structural characteristics.
Peng-Ju , Tian +3 more
core +2 more sources
Covalent organic frameworks (COFs) for CO2 utilizations
The levels of greenhouse gases, and in particular, carbon dioxide (CO2) emissions due to anthropogenic activities, have greatly inflated, and this has contributed to climate fluctuation and global warming.
Maha H. Alenazi +6 more
doaj +1 more source
Redox-Conductivity in Covalent Organic Frameworks
Electroactive covalent organic frameworks (COFs) are attracting intense research interest due to their diverse applications in energy and environmental technologies. However, the underlying electron transport mechanism is not fully understood yet. Herein, we present experimental evidence that electron transport through electroactive COFs can operate ...
Xin Hong +4 more
openaire +1 more source
Electron‐Deficient Linkers Enhance H2O2 Electrosynthesis in Covalent Organic Frameworks
Linker π‐conjugation modulates the electronic state of the Ni–N4 centers and their interaction with the key *OOH intermediate while preserving the primary coordination motif. NiPc‐PTDA delivers an H2O2 selectivity of 92% and a production rate of 34.8 mol gcat−1 h−1, highlighting linker electronic properties as a molecular design parameter for NiPc ...
Houting Xie +7 more
wiley +1 more source
Metal–Organic Frameworks and Covalent Organic Frameworks: Emerging Advances and Applications
Christopher W. Jones
doaj +1 more source
Ground‐State Charge‐Transfer Doping in Donor–Acceptor Semiconducting Polymers
This work demonstrates controlled ground‐state charge‐transfer complex formation (GS‐CTC) and doping in a series of diketopyrrolopyrrole‐based donor–acceptor semiconducting polymers paired with a π‐conjugated penta‐t‐butylpentacyanopentabenzo[25]annulene “cyanostar” macrocycle. Complementary experimental techniques show how subtle molecular, electronic,
Tanner L. Smith +13 more
wiley +1 more source
Hydrazone-linked covalent organic frameworks for membrane separation
Covalent organic frameworks (COFs), which are porous crystalline materials built using reticular and dynamic covalent chemistry, are attracting significant interest in advanced membrane separations.
Jingsi Yuan +9 more
doaj +1 more source

