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Dual engineering of thermodynamics and kinetics in covalent organic frameworks for separation. [PDF]
Nat CommunRao ZR +5 more
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Data-Driven Synthesis of Covalent Organic Frameworks via Machine Learning with Integrated Success-Failure Data. [PDF]
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Angewandte Chemie - International Edition, 2020
AbstractMany sophisticated chemical and physical properties of porous materials strongly rely on the presence of the metal ions within the structures. Whereas homogeneous distribution of metals is conveniently realized in metal–organic frameworks (MOFs), the limited stability potentially restricts their practical implementation.
Jinqiao Dong, Yan Liu, Han Xing
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AbstractMany sophisticated chemical and physical properties of porous materials strongly rely on the presence of the metal ions within the structures. Whereas homogeneous distribution of metals is conveniently realized in metal–organic frameworks (MOFs), the limited stability potentially restricts their practical implementation.
Jinqiao Dong, Yan Liu, Han Xing
exaly +3 more sources
Chemistry of Covalent Organic Frameworks
Accounts of Chemical Research, 2015Linking organic molecules by covalent bonds into extended solids typically generates amorphous, disordered materials. The ability to develop strategies for obtaining crystals of such solids is of interest because it opens the way for precise control of the geometry and functionality of the extended structure, and the stereochemical orientation of its ...
Felipe Gandara +2 more
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Accounts of Chemical Research
ConspectusMetal-organic frameworks (MOFs) and covalent organic frameworks (COFs), as emerging porous crystalline materials, have attracted remarkable attention in chemistry, physics, and materials science. MOFs are constructed by metal clusters (or ions) and organic linkers through coordination bonds, while COFs are prepared by pure organic building ...
Rong-Jia Wei, Guo-Hong Ning
exaly +3 more sources
ConspectusMetal-organic frameworks (MOFs) and covalent organic frameworks (COFs), as emerging porous crystalline materials, have attracted remarkable attention in chemistry, physics, and materials science. MOFs are constructed by metal clusters (or ions) and organic linkers through coordination bonds, while COFs are prepared by pure organic building ...
Rong-Jia Wei, Guo-Hong Ning
exaly +3 more sources
Macromolecular Rapid Communications, 2023
The dream to prepare well-defined materials drives the methodological evolution for molecular synthesis, structural control and materials manufacturing. Among various methods, chemical approaches to design, synthesize, control and engineer small molecules, polymers and networks offer the fundamental strategies.
Qianrong Fang, Shengqian Ma
+11 more sources
The dream to prepare well-defined materials drives the methodological evolution for molecular synthesis, structural control and materials manufacturing. Among various methods, chemical approaches to design, synthesize, control and engineer small molecules, polymers and networks offer the fundamental strategies.
Qianrong Fang, Shengqian Ma
+11 more sources
Covalent Organic Framework Nanohydrogels
Journal of the American Chemical Society, 2023Nanohydrogelation of covalent organic frameworks (COFs) will undoubtedly open up new applications for them in water, such as aqueous catalysis and biomedicine. It is currently a great challenge to achieve water dispersion of COFs through either bottom-up construction strategies or top-down exfoliating technologies.
Xin Tao +9 more
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2022
Structural periodicity, abundant porosity and functional diversity are characteristics of covalent organic frameworks (COFs). Among others, they are used as protective exteriors to incorporate biomolecules in order to enhance their stability and applications. An in-depth view of linkage and host-guest chemistry as well as industrial applications.
Wei Wang, Yao Chen
+4 more sources
Structural periodicity, abundant porosity and functional diversity are characteristics of covalent organic frameworks (COFs). Among others, they are used as protective exteriors to incorporate biomolecules in order to enhance their stability and applications. An in-depth view of linkage and host-guest chemistry as well as industrial applications.
Wei Wang, Yao Chen
+4 more sources
Covalent Organic Frameworks in Separation
Annual Review of Chemical and Biomolecular Engineering, 2020In the wake of sustainable development, materials research is going through a green revolution that is putting energy-efficient and environmentally friendly materials and methods in the limelight. In this quest for greener alternatives, covalent organic frameworks (COFs) have emerged as a new generation of designable crystalline porous polymers for a ...
Saikat, Das, Jie, Feng, Wei, Wang
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Chemical Society Reviews, 2012
Covalent organic frameworks (COFs) are a class of crystalline porous polymers that allow the atomically precise integration of organic units to create predesigned skeletons and nanopores. They have recently emerged as a new molecular platform for designing promising organic materials for gas storage, catalysis, and optoelectronic applications.
Xiao, Feng +2 more
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Covalent organic frameworks (COFs) are a class of crystalline porous polymers that allow the atomically precise integration of organic units to create predesigned skeletons and nanopores. They have recently emerged as a new molecular platform for designing promising organic materials for gas storage, catalysis, and optoelectronic applications.
Xiao, Feng +2 more
openaire +2 more sources