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Advances in the Synthesis of Covalent Triazine Frameworks. [PDF]

open access: yesACS Omega, 2023
Covalent triazine frameworks (CTFs) are a class of organic polymer materials constructed by aromatic 1,3,5-triazine rings with planar π-conjugation properties.
Liao L   +9 more
europepmc   +4 more sources

Development of Covalent Triazine Frameworks as Heterogeneous Catalytic Supports. [PDF]

open access: yesPolymers (Basel), 2019
Covalent triazine frameworks (CTFs) are established as an emerging class of porous organic polymers with remarkable features such as large surface area and permanent porosity, high thermal and chemical stability, and convenient functionalization that ...
Tahir N   +3 more
europepmc   +7 more sources

Covalent Triazine Frameworks via a Low-Temperature Polycondensation Approach. [PDF]

open access: yesAngew Chem Int Ed Engl, 2017
AbstractCovalent triazine frameworks (CTFs) are normally synthesized by ionothermal methods. The harsh synthetic conditions and associated limited structural diversity do not benefit for further development and practical large‐scale synthesis of CTFs. Herein we report a new strategy to construct CTFs (CTF‐HUSTs) via a polycondensation approach, which ...
Wang K   +8 more
europepmc   +7 more sources

Room-temperature methanol synthesis via CO2 hydrogenation catalyzed by cooperative molybdenum centres in covalent triazine frameworks [PDF]

open access: yesNature Communications
Selective hydrogenation of CO2 into methanol offers an ideal route for the utilization of greenhouse gas, but it remains a great challenge to be carried out under mild conditions due to the intrinsic chemical stability of CO2.
Shengliang Zhai   +8 more
doaj   +3 more sources

Construction of High‐Performance Anode of Potassium‐Ion Batteries by Stripping Covalent Triazine Frameworks with Molten Salt [PDF]

open access: yesAdvanced Science
Covalent triazine frameworks (CTFs) are promising battery electrodes owing to their designable functional groups, tunable pore sizes, and exceptional stability.
Jingyi Zhang   +9 more
doaj   +3 more sources

Immobilized covalent triazine frameworks films as effective photocatalysts for hydrogen evolution reaction [PDF]

open access: yesNature Communications, 2021
While covalent triazine frameworks are promising photocatalytic materials, it is challenging to prepare large-scale thin films. Here, authors report an interfacial polymerization method to prepare photocatalytic covalent triazine framework thin films ...
Xunliang Hu   +4 more
doaj   +2 more sources

Rigid Nanoporous Urea-Based Covalent Triazine Frameworks for C2/C1 and CO2/CH4 Gas Separation [PDF]

open access: yesMolecules, 2021
C2/C1 hydrocarbon separation is an important industrial process that relies on energy-intensive cryogenic distillation methods. The use of porous adsorbents to selectively separate these gases is a viable alternative.
Chidharth Krishnaraj   +4 more
doaj   +2 more sources

Phase engineering of covalent triazine frameworks to enhance photocatalytic hydrogen evolution performance. [PDF]

open access: yesChem Sci
Photocatalytic water splitting for hydrogen production has been considered as an effective approach to address the current energy crisis and environmental challenges.
Wu P   +8 more
europepmc   +2 more sources

Thiophene-Based Covalent Triazine Frameworks as Visible-Light-Driven Heterogeneous Photocatalysts for the Oxidative Coupling of Amines [PDF]

open access: yesMolecules
This study reports on a metal-free Covalent Triazine Framework (CTF) incorporating bithiophene structural units (TP-CTF) with a semicrystalline structure as an efficient heterogeneous photocatalyst under visible light irradiation.
Manuel Melero   +2 more
doaj   +2 more sources

Sacrificial Synthesis of Supported Ru Single Atoms and Clusters on N‐doped Carbon Derived from Covalent Triazine Frameworks: A Charge Modulation Approach [PDF]

open access: yesAdvanced Science, 2021
High‐temperature pyrolysis of nitrogen (N)‐rich, crystalline porous organic architectures in the presence of a metal precursor is an important chemical process in heterogeneous catalysis for the fabrication of highly porous N‐carbon‐supported metal ...
Zihao Zhang   +10 more
doaj   +2 more sources

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