Results 51 to 60 of about 1,891 (200)

Crosslinking of Linear Polyimines Into Aminal‐Linked Porous Organic Polymers for C2 Hydrocarbon/Methane Separation

Angewandte Chemie, EarlyView.
Crosslinking of linear polyimines with aromatic diamines via nucleophilic addition converts nonporous polyimine precursors into aminal‐linked porous networks, offering a new strategy for synthesizing porous organic polymers. The resulting materials exhibit high C2 hydrocarbon adsorption capacity, excellent selectivity over CH4, and durable cyclic ...
Xuejie Li, Yayu Yan, Qiaohong Li, Michelle Åhlén, Chao Xu   +4 more
wiley   +2 more sources

Fe doped carbon/COFs electro-spinning nanofiber for selective adsorption and photocatalytic degradation on dye pollutant by confining effect in treatment of water

Environmental Chemistry and Ecotoxicology
In this study, a novel Fe doped carbon/COF nanofibrous membrane was prepared for selective adsorption and efficiently photocatalytic degradation on dyes.
De-yu Tang, Tian-mi Wang, Ling-ling Yan, Ke-yu Long, Luo-lin Deng, Zhi-chuan Shi, Juan Lin, Qing-han Zhou   +7 more
doaj   +1 more source

Geomag Mimetic Dynamically Reconfigurable POSS Framework Enables Antifatigue Solid Electrolyte Interphases for Lithium Metal Anodes

Advanced Science, EarlyView.
A Geomag‐inspired dynamically reconfigurable POSS framework is constructed to form an antifatigue solid electrolyte interphase (SEI) for lithium metal anodes. The rigid POSS nanocages and reversible hydrogen‐bonded junctions enable adaptive stress dissipation and stable Li+ transport during repeated plating/stripping, thereby suppressing dendrite ...
Tianyi Wang, Wei Gu, Yu Liu, Di He, Zairan Xiao, Zixia Lin, Tao Huang, Jiabao Li, Hui Chong, Yaojie Lei, Xiaobo Zheng, Bing Sun, Guoxiu Wang, Chengyin Wang   +13 more
wiley   +1 more source

Recent advances in photocatalytic hydrogen peroxide production

PhotoMat, EarlyView., 2023
We classify the representative photocatalytic materials for photosynthesis of hydrogen peroxide (H2O2) in recent years and discuss the related modification methods in detail, providing inspiration and insights for the future design of photocatalysts for H2O2 production.
Jinyu Yan, Yuan Li, Yunxiang Li, Shuxin Ouyang, Tierui Zhang   +4 more
wiley   +1 more source

Semiconducting Covalent Organic Frameworks Based on Spin‐Delocalized Trioxotriangulene Neutral Radicals

Angewandte Chemie, EarlyView.
Imine‐linked 2D covalent organic frameworks incorporating delocalized trioxotriangulene (TOT) neutral radicals were synthesized through complementary routes. Direct incorporation of an amine‐functionalized TOT radical yields a highly crystalline, porous framework (TOT‐COF‐H) with intrinsic semiconducting behavior (σRT = 1.2 × 10−4 S cm−1) and a narrow ...
Paula Escamilla, Sara Trigo‐Pérez, Rafael Ramos, Ricardo Ortiz, Manuel Vilas‐Varela, Diego Peña, Manuel Melle‐Franco, Francisco Rivadulla, Manuel Souto   +8 more
wiley   +2 more sources

Nitrogen-rich covalent triazine frameworks as efficient supports for nickel-catalyzed CO2 conversion

Journal of CO2 Utilization
A nitrogen-rich covalent triazine framework (CTF) with a low carbon-to-nitrogen (C/N) molar ratio of 1.46 was synthesized as a solid nitrogen-containing ligand, offering abundant coordination sites for the immobilization of nickel(II) acetate catalyst ...
Mohadeseh Rashvand, Mojtaba Khorasani
doaj   +1 more source

Electrolyte–Framework Matching in High‐Voltage TEMPO‐COF Cathodes for Lithium Batteries

Advanced Science, EarlyView.
TEMPO‐functionalized covalent organic frameworks are investigated as high‐voltage cathodes for lithium batteries. Screening five electrolyte anions identifies lithium difluoro(oxalato)borate (LiDFOB) as the optimal electrolyte, balancing capacity, rate capability, and cycling stability, while buckypaper electrodes achieve high mass loading (40 mg cm−2)
Marilyn Esclance DMello, Nagaraj Patil, Fanni Fekecs, Sergio Pinilla, Rebeca Marcilla, Manuel Souto   +5 more
wiley   +1 more source

Kinetically Stable Boron‐Heteroatom Bonds

Angewandte Chemie, EarlyView.
This study investigates the kinetic stability of boron‐heteroatom bonds in N‐methyliminodiacetic acid (MIDA) boronates. The hemilabile nature of the ligand enables the synthesis of molecules that would otherwise be considered too hydrolytically labile. Depending on the structure, acid‐promoted migration of the boryl group was found to produce compounds
Alina Trofimova, Ben Zhen Huang, Harjeet S. Soor, Brandon White, Aleksandra Holownia, Yury Lebedev, Alan J. Lough, Travis Dudding, Andrei K. Yudin   +8 more
wiley   +2 more sources

Tailoring topology and bio-interactions of triazine frameworks

Scientific Reports
The construction of covalent organic frameworks with special geometery and optical properties is of high interest, due to their unique physicochemical and biological properties.
Sara Bagheri, Mohsen Adeli, Abedin Zabardasti, Siamak Beyranvand   +3 more
doaj   +1 more source

Synthesis of a novel freestanding conjugated triazine-based microporous membrane through superacid-catalyzed polymerization for superior CO2 separation

Chemical Engineering Journal Advances, 2022
This study aims at developing a novel freestanding conjugated triazine-based membrane (ETM-1) with permanent porosity via a low-temperature superacid-promoted polymerization reaction.
Sina Pourebrahimi, Majid Pirooz
doaj   +1 more source