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Abstract Treatment of cis- or trans-CpRe(CO)2Br2 (1) with Ph3SnH yields the corresponding dihydride CpRe(CO)2H2 (2) and Ph3SnBr. Conducting the same reaction in the presence of pyridine or Et3N gives trans-CpRe(CO)2(SnPh3)2 (3). The molecular structure of 3 has been determined by X-ray crystallography.
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