Results 11 to 20 of about 130,996 (253)

Transition Metal Catalyzed Hiyama Cross-Coupling: Recent Methodology Developments and Synthetic Applications

open access: yesMolecules, 2022
Hiyama cross-coupling is a versatile reaction in synthetic organic chemistry for the construction of carbon–carbon bonds. It involves the coupling of organosilicons with organic halides using transition metal catalysts in good yields and high ...
Rida Noor   +7 more
doaj   +1 more source

A DFT Study on FeI/FeII/FeIII Mechanism of the Cross-Coupling between Haloalkane and Aryl Grignard Reagent Catalyzed by Iron-SciOPP Complexes

open access: yesMolecules, 2020
To explore plausible reaction pathways of the cross-coupling reaction between a haloalkane and an aryl metal reagent catalyzed by an iron–phosphine complex, we examine the reaction of FeBrPh(SciOPP) 1 and bromocycloheptane employing density functional ...
Akhilesh K. Sharma, Masaharu Nakamura
doaj   +1 more source

Aminocatalytic stereoselective synthesis of (E)-α-naphthyl enals via cross-coupling-like reaction of 1-bromo-2-naphthols with enals

open access: yesGreen Synthesis and Catalysis, 2021
A diphenyl prolinol TMS ether-catalyzed stereoselective reaction of 1-bromo-2-naphthols with enals has been developed. The organocatalyzed cross coupling-like reaction servers an efficient approach to sterically congested (E)-α-naphthyl enals. The formal
Xixi Song   +4 more
doaj   +1 more source

Mechanochemical synthesis of some heterocyclic molecules using Sonogashira cross-coupling reaction and their anticancer activities

open access: yesResults in Chemistry, 2020
A greener strategy for the synthesis of some functionalized heterocycles have been developed using Sonogashira cross-coupling reaction of furfural derived isoxazolidine and isoxazoline derivatives.
Bhaskar Chakraborty, Esmita Chettri
doaj   +1 more source

Mechanistic Implications for the Ni(I)-Catalyzed Kumada Cross-Coupling Reaction

open access: yesInorganics, 2017
Herein we report on the cross-coupling reaction of phenylmagnesium bromide with aryl halides using the well-defined tetrahedral Ni(I) complex, [(Triphos)NiICl] (Triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane).
Linda Iffland   +3 more
doaj   +1 more source

Vinyl Esters and Vinyl Sulfonates as Green Alternatives to Vinyl Bromide for the Synthesis of Monosubstituted Alkenes via Transition-Metal-Catalyzed Reactions

open access: yesChemistry, 2023
This review summarizes the applications of vinyl sulfonate and vinyl acetate as green alternatives for vinyl bromide in cross-coupling reactions. In the first part, the preparation of vinyl sulfonates and their cross-coupling reactions are briefly ...
Tomáš Tobrman
doaj   +1 more source

Research progress of supported palladium catalysts for Suzuki cross-coupling reaction of aryl chlorides

open access: yes上海师范大学学报. 自然科学版, 2020
The palladium(Pd)-catalyzed cross-coupling reaction between organic boricacids and aryl halides provides a powerful and general method for the formation of carbon-carbon bonds known as the Suzuki cross-coupling.It was found that with the cheap and ...
TANG Yong   +3 more
doaj   +1 more source

Prospects and Applications of Palladium Nanoparticles in the Cross‐coupling of (hetero)aryl Halides and Related Analogues

open access: yesChemistryOpen, 2021
Discovering efficient methods for the formation of carbon‐carbon bonds is a central ongoing theme in organic synthesis. Cross‐coupling reactions catalysed by metal nanoparticles are attractive alternatives to the traditional use of metal counterparts due
Jude I. Ayogu, Efeturi A. Onoabedje
doaj   +1 more source

Biaryl Product Formation from Cross-coupling in Palladiumcatalyzed Borylation of a Boc Protected Aminobromoquinoline Compound

open access: yesMolecules, 2004
The palladium catalyzed borylation of a Boc protected aminobromoquinoline compound with bis(pinacolato)diboron yielded a biaryl compound, resulting from cross coupling, as the major product, instead of the intended boronate, even though no strong base ...
Binghe Wang, Jun Yan, Hao Fang
doaj   +1 more source

Palladium-catalyzed cross-couplings in the synthesis of agrochemicals

open access: yesAdvanced Agrochem, 2022
Palladium-catalyzed cross-couplings have played an increasingly important role in the synthesis of agrochemicals. In this review, the applications of palladium-catalyzed Heck reaction, Suzuki-Miyaura cross-coupling, Sonogashira coupling, Negishi cross ...
Yuxin Zhu, Wenfeng Dong, Wenjun Tang
doaj   +1 more source

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