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We propose a suture‐complementary approach that integrates optical skin clearing with a strain‐programmable luminescent adhesive patch. Hyaluronic acid promotes transdermal delivery of tartrazine to improve optical clearing and stabilizes its interaction with a photosensitizer. Optical clearing increases the penetration depth of visible light into skin,
Seong‐Jong Kim +6 more
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Cross-Coupling Reactions of Nitroarenes
Accounts of Chemical Research, 2021Cross-coupling reactions are powerful synthetic tools to construct diverse chemical bonds often found in, for example, advanced materials and pharmaceuticals. Since their discovery, haloarenes have habitually been used as electrophilic coupling partners both in academic and industrial contexts.
Myuto Kashihara, Yoshiaki Nakao
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Iron-Catalyzed Cross-Coupling Reactions
Journal of the American Chemical Society, 2002Simple iron salts such as FeCl(n), Fe(acac)(n) (n = 2,3) or the salen complex 4 turned out to be highly efficient, cheap, toxicologically benign, and environmentally friendly precatalysts for a host of cross-coupling reactions of alkyl or aryl Grignard reagents, zincates, or organomanganese species with aryl and heteroaryl chlorides, triflates, and ...
Fürstner, A. +3 more
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On-Surface Cross-Coupling Reactions
The Journal of Physical Chemistry Letters, 2023On-surface synthesis, as a bottom-up synthetic method, has been proven to be a powerful tool for atomically precise fabrication of low-dimensional carbon nanomaterials over the past 15 years. This method relies on covalent coupling reactions that occur on solid substrates such as metal or metal oxide surfaces under ultra-high-vacuum conditions, and the
Guang-Yan Xing +3 more
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Cobalt-Catalyzed Cross-Coupling Reactions
Chemical Reviews, 20102 ...
Cahiez, Gerard, Moyeux, Alban
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Cobalt-catalyzed cross-coupling reactions
Chemical Communications, 2008In the last few years, we and other groups have demonstrated that economical cobalt salts can advantageously replace expensive and toxic catalysts for cross coupling reactions. These cobalt-catalyzed reactions have considerably extended the range of functionalized compounds.
Gosmini, Corinne +2 more
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Selected Patented Cross-Coupling Reaction Technologies
Chemical Reviews, 2006AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Jean-Pierre, Corbet, Gérard, Mignani
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Mechanochemical Cross-Coupling Reactions
Trends in Chemistry, 2020In recent years, solvent-less mechanochemical organic transformations using ball milling have come to the forefront of organic synthesis as cleaner and sustainable synthetic alternatives. Apart from the environmental benefits, mechanochemical approaches potentially enable access to novel chemical space that has reactivities and selectivities different ...
Koji Kubota, Hajime Ito
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Negishi cross-coupling reaction
2002The Negishi cross-coupling reaction is the nickel- or palladium-catalyzed coupling of organozinc compounds with various halides or triflates (aryl, alkenyl, alkynyl, and acyl).
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