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Cooperative effects in multivalent crown ether/ammonium assemblies
Krbek, Larissa Katharina Sophie von
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Crown ethers in hydrogenated graphene
Physical Chemistry Chemical Physics, 2021Graphane could serve as an ideal platform to rigidify the highly flexible crown ethers, which will greatly improve the binding strength and selectivity of crown ethers with metal cations and open up new applications for crown ethers and graphane.
Kai Guo +8 more
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UNSATURATED CROWN ETHERS: STILBENO-CROWN ETHERS
Chemistry Letters, 1982Abstract Stilbenocrown ethers 3a,c and 4a,b were synthesized in a cyclization reaction of benzoin with oligoethylene glycol ditosylates(2a-c) under a phase-transfer condition. Extractions of aqueous alkali picrates(Na+–Cs+) were examined with the distilbenocrown ethers 4a,b, the partially-hydrogenated tetraphenylcrown ethers 6a,b and the
Yoshihisa Inoue +4 more
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From Crown Ethers to Zeolites: Reaction of EtAlCl2 with Crown Ethers
Journal of Inclusion Phenomena, 1984In contrast to aluminum alkyls, alkyl aluminum halides such as EtAlCl2 react with crown ethers to form cation-anion pairs which exhibit the liquid clathrate effect. Specifically, [12-C-4-·AlCl2][AlCl3Et] and [18-C-6·AlCl2][AlCl3Et] have been isolated and characterized by X-ray diffraction techniques.
Jerry L. Atwood +5 more
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Tetrahedron, 1980
Abstract The stability constants for the 1:1 complexes of 1,7,10,16-tetraoxa-4, 13-diazacyclooctadecane and 4,7,13,16,21,24-hexaoxa-1, 10-diazabicyclo[8,8,8]hexacosane with Na+, K+, Rb+ and Cs+ have been determined in acetonitrile at 25.0°C by conductivity measurements. The stability constants are considerably higher, and the selectivity is different,
S. Kulstad, L.Å. Malmsten
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Abstract The stability constants for the 1:1 complexes of 1,7,10,16-tetraoxa-4, 13-diazacyclooctadecane and 4,7,13,16,21,24-hexaoxa-1, 10-diazabicyclo[8,8,8]hexacosane with Na+, K+, Rb+ and Cs+ have been determined in acetonitrile at 25.0°C by conductivity measurements. The stability constants are considerably higher, and the selectivity is different,
S. Kulstad, L.Å. Malmsten
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Journal of Inclusion Phenomena and Molecular Recognition in Chemistry, 1988
The discovery of the crown ethers stemmed from efforts to control the catalytic activity of vanadium and copper by complexation with multidentate ligands. The first crown ether, 2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclo-octadeca-2,11-diene, was obtained in 0.4% yield during an attempt to prepare a phenolic ligand from catechol and bis(2-chloroethyl)
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The discovery of the crown ethers stemmed from efforts to control the catalytic activity of vanadium and copper by complexation with multidentate ligands. The first crown ether, 2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclo-octadeca-2,11-diene, was obtained in 0.4% yield during an attempt to prepare a phenolic ligand from catechol and bis(2-chloroethyl)
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Antifungal Activity of Crown Ethers
Journal of Inclusion Phenomena, 1984Some crown ethers were found to show significant antifungal activity against some wood-decay fungi, phytopathogenic fungi and eumycetes,Trichophytons for dermatomycosis. Their toxicity was evaluated by the paper disc method as well as by determining the values of ED50, i.e., the concentration which inhibits the mycelium growth by 50%.
Koji Yagi +5 more
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Novel crown ethers by oxidative cycloaddition of thiopheno crown ethers
Journal of the Chemical Society, Perkin Transactions 1, 1994The synthesis of the thiopheno crown ethers 4 is described. The oxidative cycloaddition of these and the known thiopheno crown ethers 2 with N-phenylmaleimide is reported. The resulting sulfoxy-bridged cycloadducts 15 and 16 are transformed oxidatively into the phthalimido crown ethers 14 and 17.
YuanQiang Li +3 more
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