Results 141 to 150 of about 303,895 (348)

Enantioconvergent Access to Chiral S(VI) Stereocenters by Kinetic Resolution of Sulfonimidoyl Chlorides

open access: yesAngewandte Chemie, EarlyView.
An enantioconvergent approach for the kinetic resolution of S(VI) stereocenters that leverages the electrophilic reactivity of the chiral sulfur atom is described. The catalytic process provides access to sulfonimidoyl chlorides and sulfonimidates, which are among the least studied S(VI) functionalities.
Arko Das   +10 more
wiley   +2 more sources

AI‐Driven Predictive Design and Functionalization of Three Dimensional‐Printed PEEK Implants with Tryptophan‐Enriched Alginate Hydrogel for Enhanced Biomimetic Surface Performance

open access: yesAdvanced Intelligent Systems, EarlyView.
This study introduces an AI‐guided strategy to design 3D‐printed PEEK implants functionalized with a tryptophan‐enriched alginate hydrogel (TRYALPEEK). The modification improves hydrophilicity, reduces surface roughness, enhances cytocompatibility, and optimizes stress distribution. The platform offers a promising route for personalized implant design,
Wafa Benaatou   +8 more
wiley   +1 more source

Multivalent Crown Ether Receptors Enable Allosteric Regulation of Anion Exchange in an Fe4L6 Tetrahedron

open access: green, 2018
Larissa K. S. von Krbek   +4 more
openalex   +2 more sources

Participation for mental health service development in China: Conditions, challenges, facilitators, and outcomes

open access: yesAmerican Journal of Community Psychology, EarlyView.
Abstract This study analyzes a participatory project to develop peer support services for people with serious mental illnesses (SMIs) in China. Drawing on interviews with psychiatrists, social workers, service users, and a family caregiver, it examines the conditions, challenges, facilitators, and outcomes of participation in a paternalistic context ...
Zhiying Ma   +6 more
wiley   +1 more source

Reactivity of Low Valent Magnesium(I) Complexes with Epoxides and Episulfides

open access: yesAngewandte Chemie, EarlyView.
C–H functionalisation and ether cleavage are typically performed by aggressive organolithium reagents. Unveiling the untapped Brønsted basicity of magnesium‐oxo species, the reaction of Mg(I) precursors with epoxides initially proceeds via deoxygenation, followed by deprotonation and rearrangement of a second epoxide.
Peter J. Shaw   +2 more
wiley   +2 more sources

Synthetic Motifs for Understanding Lewis Acid Interactions with Persulfides and Thioselenides

open access: yesAngewandte Chemie, EarlyView.
Using isolated dichalcogenides as precursors, we report the synthesis, characterization, and reactivity of Zn persulfide and thioselenide complexes. 77Se NMR shows distinct impacts to electronic structure and reactivity between different thioselenides coordinated to different Lewis acids.
Keyan Li   +3 more
wiley   +2 more sources

Evaluation of solid-supported room-temperature ionic liquids containing crown ethers as media for metal ion separation and preconcentration

open access: green, 2014
Cory A. Hawkins   +5 more
openalex   +2 more sources

Home - About - Disclaimer - Privacy