Results 151 to 160 of about 303,895 (348)

Stabilization of the Benzene Radical Trianion in an Inverse‐Sandwich Yttrium Complex

open access: yesAngewandte Chemie, EarlyView.
A new type of benzene anion state is born: The unprecedented benzene radical trianion embedded in an inverse‐sandwich yttrium complex was synthesized by a one‐electron chemical reduction of its benzene dianion precursor using potassium graphite in the presence of [2.2.2]‐cryptand.
Weiqing Mao   +5 more
wiley   +2 more sources

Template‐Controlled Mechanochemical Dissociation of a Rotaxane

open access: yesAngewandte Chemie, EarlyView.
The presence or absence of the Pd template used in rotaxane formation selectively leads to two different mechanochemical dissociation pathways. The Pd maintains a smaller cavity size that favors dissociation by unstoppering. Removal of the Pd template atoms increases the size and flexibility of the macrocycle, which allows for disassembly by ...
James Ormson   +2 more
wiley   +2 more sources

Evaluation of Dental Crowns Made in the School of Dentistry of Qom University of Medical Sciences, 2018 (Iran)

open access: yesMajallah-i Dānishgāh-i ̒Ulūm-i Pizishkī-i Qum, 2019
Background and Objectives: One of the most commonly used restorations for teeth with severe crown destruction is restoration with fixed prosthesis.
Mahdieh Jamshidian   +4 more
doaj  

The Crystal Crown [PDF]

open access: yesMayo Clinic Proceedings, 2019
Hasan Ahmad Hasan Albitar   +1 more
openaire   +2 more sources

Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes

open access: yesAngewandte Chemie, EarlyView.
A photocatalytic formal hydrocarbamoylation reaction that employs a cyanate anion as the C1 source and provides N‐acyl iminophosphorane products from activated alkenes is described. Mechanistic investigations suggest generation of a phosphoranyl radical by addition of the cyanate anion to a phosphine radical cation, which enables the delivery of the ...
Petra Vojáčková, Armido Studer
wiley   +2 more sources

Closing a gap in tropical forest biomass estimation: accounting for crown mass variation in pantropical allometries

open access: gold, 2015
Pierre Ploton   +23 more
openalex   +1 more source

Taming of Low‐Valent Arsenic Compounds and Transfer of Nascent As2 Facilitated by a Frustrated Lewis Pair

open access: yesAngewandte Chemie, EarlyView.
A series of frustrated Lewis pair (FLP) stabilized arsenic compounds with formal oxidation numbers at As of +1, 0, and −1 are presented. A stable FLP‐chelated complex of As2 was prepared which undergoes the light‐induced release of nascent diarsenic, As2nasc, which reveals clean triple‐bond type reactivity with dienes and metal‐metal bonds under mild ...
Ludwig Zapf   +3 more
wiley   +2 more sources

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