Results 181 to 190 of about 221,519 (349)

Reversible Mechanical Interlocking via Stimuli‐Triggered Nonhomeomorphic Topology Transformation Enables Highly Efficient Rotaxane Synthesis

open access: yesAngewandte Chemie, EarlyView.
We design the macrocycles capable of stimuli‐triggered, reversible transformation between nonhomeomorphic topologies (one‐hole ring versus two‐hole figure‐eight ring). By leveraging the ring size change associated with the topology transformation, we achieve reagent‐free, highly efficient, reversible, and one‐pot synthesis of [2]rotaxane and bis[2 ...
Chunlin Xiao   +6 more
wiley   +1 more source

Spatial Assembly of Mechanically Planar Chiral Rotaxanes on Rationally Designed Cavitands

open access: yesAngewandte Chemie, EarlyView.
A spatial molecular assembly strategy enables the synthesis of enantioenriched mechanically planar chiral rotaxanes. Inherently chiral cavitands are rationally designed to encode and transmit the stereochemical information. Predictable stereochemical induction is achieved by controlling the spatial arrangement of molecular components through ...
Liwen Xia   +3 more
wiley   +2 more sources

Synthesis, Isolation, and Reactivity of a Phosphinidene Telluride

open access: yesAngewandte Chemie, EarlyView.
We describe the synthesis and isolation of a phosphinidene telluride. This species acts as a versatile phosphinidene transfer reagent accompanied by the extrusion of elemental tellurium. Abstract The synthesis and isolation of a phosphorus(III) telluride is reported.
Chenyang Hu   +4 more
wiley   +2 more sources

Self‐Assembled Polypseudorotaxanes Crosslinked by Dynamic Disulfide Bonds as Modular Functionalization for Thiophilic Metal Nanoparticles

open access: yesAngewandte Chemie, EarlyView.
Self‐assembled thiol‐rich polypseudorotaxanes with high modularity were developed via a “one‐pot” preparation through the threading of thiolated α‐cyclodextrins on polymers and subsequent oxidation of thiols into disulfide bonds. This dynamic motif was used as a functionalization platform for thiophilic metal nanoparticles, either tethering them to a ...
Xiang Xu   +12 more
wiley   +1 more source

Home - About - Disclaimer - Privacy