Direct synthesis of cyanate anion from dinitrogen catalysed by molybdenum complexes bearing pincer-type ligand [PDF]
Direct conversion of dinitrogen to organonitrogen compounds is a challenging goal in nitrogen fixation chemistry. Here, the authors report the catalytic formation of cyanate anion from dinitrogen under ambient conditions using a molybdenum complex.
Shun Suginome +2 more
exaly +3 more sources
Activation of Cyanate Anions by Phosphine Radical Cations Enables Formal Hydrocarbamoylation of Alkenes. [PDF]
A photocatalytic formal hydrocarbamoylation reaction that employs a cyanate anion as the C1 source and provides N‐acyl iminophosphorane products from activated alkenes is described. Mechanistic investigations suggest generation of a phosphoranyl radical by addition of the cyanate anion to a phosphine radical cation, which enables the delivery of the ...
Vojáčková P, Studer A.
europepmc +4 more sources
Unraveling sources of cyanate in the marine environment: insights from cyanate distributions and production during the photochemical degradation of dissolved organic matter [PDF]
Cyanate is a nitrogen and energy source for diverse marine microorganisms, playing important roles in the nitrogen cycle. Despite the extensive research on cyanate utilization, the sources of this nitrogen compound remain largely enigmatic.
Rui Wang +8 more
doaj +2 more sources
Cyanate (OCN−) is an organic nitrogen compound found in aquatic environments potentially involved in phytoplankton growth. Given the prevalence and activity of cyanate lyase genes in eukaryotic microalgae, cyanate has been suggested as an alternative ...
Nina Guérin +12 more
doaj +2 more sources
Di-Cyclohexene Oxide Bridged by DDSQ: Preparation, Characterization, and Application as Fillers for Cyanate Ester Resin [PDF]
In order to improve the dielectric properties of existing thermosetting resins, taking advantage of reactive fillers is a simple and feasible option. In this paper, we synthesized a new double epoxycyclohexane double-decker silsesquioxane (DEDDSQ), in ...
Xiaoye Gao +3 more
doaj +2 more sources
Nitrogen uptake rates and phytoplankton composition across contrasting North Atlantic Ocean coastal regimes north and south of Cape Hatteras [PDF]
Understanding nitrogen (N) uptake rates respect to nutrient availability and the biogeography of phytoplankton communities is crucial for untangling the complexities of marine ecosystems and the physical, biological, and chemical forces shaping them.
Yifan Zhu +8 more
doaj +2 more sources
Investigation on Gold Dissolution Performance and Mechanism in Imidazolium Cyanate Ionic Liquids [PDF]
To explore green gold leaching reagents, a series of imidazolium cyanate ionic liquids (ILs), 1-ethyl-3-methyl-imidazolium cyanate ([C2MIM][OCN]), 1-propyl-3-methyl-imidazolium cyanate ([C3MIM][OCN]) and 1-butyl-3-methyl-imidazolcyanate ([C4MIM][OCN ...
Na Zhang +6 more
doaj +2 more sources
A Micromechanical Study of Interactions of Cyanate Ester Monomer with Graphene or Boron Nitride Monolayer. [PDF]
Sachdeva G +3 more
europepmc +3 more sources
Alkyl Cyanates. II. A New Route to Alkyl Cyanates. [PDF]
K. A. Jensen +3 more
openaire +2 more sources
In this paper, an equimolar blend of bisphenol A dipropargyl ether and cyanate ester was selected to study the effect of different catalysts on the curing reaction of a bisphenol A dipropargyl ether and cyanate ester blended resin system, and the thermal
Chuan Li +5 more
doaj +1 more source

