Results 71 to 80 of about 1,482,034 (300)

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

Electronic Trap States in Methanofullerenes [PDF]

open access: yesAdvanced Energy Materials, 1, 655, (2011), 2011
The trap states in three fullerene derivatives, namely PC61BM ([6,6]-phenyl C61 butyric acid methyl ester), bisPC61BM (bis[6,6]-phenyl C61 butyric acid methyl ester) and PC71BM ([6,6]-phenyl C71 butyric acid methyl ester), are investigated by thermally stimulated current measurements (TSC). Thereby, the lower limit of the trap densities for all studied
arxiv   +1 more source

Reconstruction of the Microstructure of Cyanate Ester Resin by Using Prepared Cyanate Ester Resin Nanoparticles and Analysis of the Curing Kinetics Using the Avrami Equation of Phase Change

open access: yesApplied Sciences, 2019
Bisphenol A dicyanate (BADCy) resin nanoparticles were synthesized by precipitation polymerization and used to modulate the microstructure of the BADCy resin matrix. A microscopic mechanism model was used to characterize the curing process of BADCy resin
Hongtao Cao   +4 more
doaj   +1 more source

Sequence Control in Sulfur‐Containing Ring‐Opening Co‐ and Terpolymerisations

open access: yesAngewandte Chemie International Edition, Accepted Article.
Sulfur‐containing polymers uniquely expand the catalogue of accessible material properties compared to current commodity materials, yet their synthesis remains underdeveloped. Combining sulfur‐ and oxygen‐containing monomers in ring‐opening copolymerisation leads to a reshuffling reaction of the sulfur centres, which has been challenging to control — a
Bhargav R. Manjunatha   +5 more
wiley   +1 more source

Modification of cyanate resin by conjugated tri-component interpenetrating polymer networks

open access: yesJournal of Materials Research and Technology, 2017
Cyanate ester (CE) resin was modified in a multi-component way using the technology of conjugated tri-component interpenetrating polymer networks (CTC-IPN).
Wang Chuang   +5 more
doaj   +1 more source

Copper phenyl phosphonate for epoxy resin and cyanate ester copolymer with improved flame retardancy and thermal properties

open access: yese-Polymers, 2023
Epoxy resin (EP)/cyanate ester (CE) copolymer, an important structural material with high temperature resistance and low dielectric constant in aerospace, microelectronics, and related fields, is still of great flammability danger.
Cao Zhilin, Ren Changxin, Wang Zhengzhou
doaj   +1 more source

Remote functionalization by tandem radical chain reactions [PDF]

open access: yes, 1997
Normal radical relay chlorination of cholestan-3α-ol directed by an attached m-iodobenzoate ester group affords a 9α-chloro steroid, but when the same reaction is conducted in the presence of an excess of CBr4 the product is a 9α-bromo steroid ...
Wiedenfeld, David
core   +1 more source

Development of High‐Performance Ablative Composites: Synergistic Effects of Alumina Particles and Silica Fabric in the Polybenzoxazine Matrix

open access: yesPolymer Composites, EarlyView.
The illustration depicts the improvement in the mechanical and ablative properties of polybenzoxazine composites according to their alumina particle content. ABSTRACT The aerospace industry is seeking a replacement of toxic phenolics to use in ablative materials. One of the most promising candidates is polybenzoxazine materials because of their extreme
İ. Egemen Küçük   +2 more
wiley   +1 more source

METHOD OF FLUORIMETRIC DETERMINATION OF POTASSIUM CYANATE IN CARBAMYLATED DARBEPOIETIN ALPHA DRUG SUBSTANCE

open access: yesРазработка и регистрация лекарственных средств, 2019
Method of determination of potassium cyanate in carbamylated darbepoietin alpha drug substance was developed. The method is based on derivatization of cyanate by methyl ester of anthranilic acid followed by formation bicyclic derivative (1-H,3-H ...
A. D. Askretkov   +2 more
doaj  

Synergistic Effects of Functional CNTs and h-BN on Enhanced Thermal Conductivity of Epoxy/Cyanate Matrix Composites

open access: yesNanomaterials, 2018
Epoxy/cyanate resin matrix composites (AG80/CE) with improved thermal conductivity and mechanical properties were obtained with synergetic enhancement with functional carbon nanotubes (f-CNTs) and hexagonal boron nitride (h-BN).
Mingzhen Xu   +5 more
doaj   +1 more source

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