Results 31 to 40 of about 804 (154)

Potassium‐Ligand Cooperation Facilitated Chemical Bond Activation and Catalytic Hydrogenation

open access: yesAngewandte Chemie, Volume 138, Issue 28, 6 July 2026.
A new strategy for alkali metal‐mediated catalysis based on metal–ligand cooperation (MLC) is presented. Potassium pincer complexes exhibit remarkable reactivity toward a range of molecules via an unprecedented potassium–ligand cooperative mechanism. This reactivity enables potassium‐catalyzed hydrogenation, providing efficient reduction of ketones and
Yaoyu Liang   +6 more
wiley   +2 more sources

Enhanced Urea Oxidation Reaction by Mn‐Doped Nickel Hydroxide From Wastewater

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Mn incorporation modifies the hydroxide structure and modulates the electronic properties of the Ni centers, promoting the formation of catalytically active NiOOH species. Mn dopants induce a favorable electronic effect but do not directly participate in the UOR mechanism, enhancing the overall urea oxidation rate and resulting in increased hydrogen ...
Filippo Bano   +8 more
wiley   +1 more source

Progress report on new epilepsy treatments: A summary of the Eighteenth Eilat Conference on New Antiepileptic Drugs and Devices (EILAT XVIII). I. Treatments in preclinical and early clinical development

open access: yesEpilepsia, EarlyView.
Abstract Over the last 34 years, the Eilat Conference on New Antiepileptic Drugs and Devices has provided an interactive forum for stakeholders to discuss investigational and recently licensed treatments for seizures and epilepsy. The Eighteenth Eilat Conference on New Antiepileptic Drugs and Devices (EILAT XVIII) took place in Madrid, Spain, on May 3 ...
Meir Bialer   +7 more
wiley   +1 more source

Mechanistic Understanding of Nickel Catalyzed Urea Oxidation Reaction to Cyanate and Nitrite

open access: yesExploration, EarlyView.
The urea oxidation reaction (UOR) is a promising alternative to oxygen evolution reaction (OER) for energy efficient hydrogen production, yet its reaction mechanism remains controversial because many proposed pathways have not been directly correlated with experimentally verified products and intermediates.
Kyu In Shim   +4 more
wiley   +1 more source

In Situ Curing‐Enabled 3D Printing of Continuous Fiber‐Reinforced Thermosetting Composites

open access: yesJournal of Polymer Science, EarlyView.
In situ curing‐enabled the 3D printing of continuous fiber/thermoset composites, which were reviewed. Particularly, four types of in situ curing, were discussed, including Radiation‐induced curing, photothermal curing, electrothermal curing, and frontal polymerization. AI‐integrated printing was also analyzed.
Xiaofei Wu   +2 more
wiley   +1 more source

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

open access: yesChemistryEurope
In contrast to the simple and straightforward generation of pyridinium cations, the P‐alkylation of the heavier homolog λ3σ2‐phosphinines is more challenging due to their weak nucleophilicity, as demonstrated only by a handful of examples. The previously
Samantha Frank   +6 more
doaj   +1 more source

Periodontitis and Rheumatoid Arthritis—Mechanistic Evidence

open access: yesJournal of Periodontal Research, EarlyView.
Periodontitis and rheumatoid arthritis are linked via the two‐hit model whereby early periodontal inflammation can lead to autoantibody production capable of interacting with inflamed synovial tissues. Subsequent systemic inflammation can exacerbate the periodontal inflammatory response and bacterial dysbiosis leading to further autoantibody production
Mark Bartold   +2 more
wiley   +1 more source

Activation of the CN Single Bond in Iso(thio)cyanates by a Phosphinine‐Borane Lewis Pair: Unravelling a Complex Reaction Network

open access: yesChemistryEurope
The first example of a CN σ‐bond activation in tert‐butyl isocyanate and isothiocyanate by a 3,5‐bis(trimethylsilyl)‐phosphinine‐B(C6F5)3 Lewis pair is reported.
Samantha Frank   +6 more
doaj   +1 more source

cyanates

open access: yes, 2014
Citation: 'cyanates' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.C01485 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms.
openaire   +1 more source

The influence of haemoglobin–O2 affinity on aerobic capacity in hypoxia in high‐altitude deer mice (Peromyscus maniculatus)

open access: yesThe Journal of Physiology, EarlyView.
Abstract figure legend The influence of haemoglobin–O2 affinity on aerobic capacity in hypoxia has been contentious. Many high‐altitude natives have greater haemoglobin–O2 affinity (lower P50, the O2 pressure at 50% haemoglobin saturation) than their low‐altitude counterparts, but the advantages of this change for aerobic metabolism have often remained
Kayla M. Garvey, Graham R. Scott
wiley   +1 more source

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